Multifunctional Reversible Self-Assembled Structures of Cellulose-Derived Phase-Change Nanocrystals

© 2020 The Authors. Advanced Materials published by Wiley-VCH GmbH.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - 33(2021), 3 vom: 25. Jan., Seite e2005263
1. Verfasser: Wang, Yonggui (VerfasserIn)
Weitere Verfasser: Qiu, Zhe, Lang, Zhen, Xie, Yanjun, Xiao, Zefang, Wang, Haigang, Liang, Daxin, Li, Jian, Zhang, Kai
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2021
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article cellulose core-shell structure phase-change nanocrystals thermal reversibility thermalimaging
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520 |a Owing to advantageous properties attributed to well-organized structures, multifunctional materials with reversible hierarchical and highly ordered arrangement in solid-state assembled structures have drawn tremendous interest. However, such materials rarely exist. Based on the reversible phase transition of phase-change materials (PCMs), phase-change nanocrystals (C18-UCNCs) are presented herein, which are capable of self-assembling into well-ordered hierarchical structures. C18-UCNCs have a core-shell structure consisting of a cellulose crystalline core that retains the basic structure and a soft shell containing octadecyl chains that allow phase transition. The distinct core-shell structure and phase transition of octadecyl chains allow C18-UCNCs to self-assemble into flaky nano/microstructures. These self-assembled C18-UCNCs exhibit efficient thermal transport and light-to-thermal energy conversion, and thus are promising for thermosensitive imaging. Specifically, flaky self-assembled nano/microstructures with manipulable surface morphology, surface wetting, and optical properties are thermoreversible and show thermally induced self-healing properties. By using phase-change nanocrystals as a novel group of PCMs, reversible self-assembled multifunctional materials can be engineered. This study proposes a promising approach for constructing self-assembled hierarchical structures by using phase-change nanocrystals and thereby significantly expands the application of PCMs 
650 4 |a Journal Article 
650 4 |a cellulose 
650 4 |a core-shell structure 
650 4 |a phase-change nanocrystals 
650 4 |a thermal reversibility 
650 4 |a thermalimaging 
700 1 |a Qiu, Zhe  |e verfasserin  |4 aut 
700 1 |a Lang, Zhen  |e verfasserin  |4 aut 
700 1 |a Xie, Yanjun  |e verfasserin  |4 aut 
700 1 |a Xiao, Zefang  |e verfasserin  |4 aut 
700 1 |a Wang, Haigang  |e verfasserin  |4 aut 
700 1 |a Liang, Daxin  |e verfasserin  |4 aut 
700 1 |a Li, Jian  |e verfasserin  |4 aut 
700 1 |a Zhang, Kai  |e verfasserin  |4 aut 
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773 1 8 |g volume:33  |g year:2021  |g number:3  |g day:25  |g month:01  |g pages:e2005263 
856 4 0 |u http://dx.doi.org/10.1002/adma.202005263  |3 Volltext 
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