Operando Tailoring of Defects and Strains in Corrugated β-Ni(OH)2 Nanosheets for Stable and High-Rate Energy Storage

© 2020 Wiley-VCH GmbH.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - 33(2021), 2 vom: 07. Jan., Seite e2006147
1. Verfasser: Li, Shaofeng (VerfasserIn)
Weitere Verfasser: Sharma, Nikhil, Yu, Chang, Zhang, Yan, Wan, Gang, Fu, Rong, Huang, Hongling, Sun, Xueyan, Lee, Sang-Jun, Lee, Jun-Sik, Nordlund, Dennis, Pianetta, Piero, Zhao, Kejie, Liu, Yijin, Qiu, Jieshan
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2021
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article defects strain supercapacitors β-Ni(OH)2
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520 |a Nickel hydroxide represents a technologically important material for energy storage, such as hybrid supercapacitors. It has two different crystallographic polymorphs, α- and β-Ni(OH)2 , showing advantages in either theoretical capacity or cycling/rate performance, manifesting a trade-off trend that needs to be optimized for practical applications. Here, the synergistic superiorities in both activity and stability of corrugated β-Ni(OH)2 nanosheets are demonstrated through an electrochemical abuse approach. With ≈91% capacity retention after 10 000 cycles, the corrugated β-Ni(OH)2 nanosheets can deliver a gravimetric capacity of 457 C g-1 at a high current density of 30 A g-1 , which is nearly two and four times that of the regular α- and β-Ni(OH)2 , respectively. Operando spectroscopy and finite element analysis reveal that greatly enhanced chemical activity and structural robustness can be attributed to the in situ tailored lattice defects and the strain-induced highly curved micromorphology. This work demonstrates a multi-scale defect-and-strain co-design strategy, which is helpful for rational design and tuned fabrication of next-generation electrode materials for stable and high-rate energy storage 
650 4 |a Journal Article 
650 4 |a defects 
650 4 |a strain 
650 4 |a supercapacitors 
650 4 |a β-Ni(OH)2 
700 1 |a Sharma, Nikhil  |e verfasserin  |4 aut 
700 1 |a Yu, Chang  |e verfasserin  |4 aut 
700 1 |a Zhang, Yan  |e verfasserin  |4 aut 
700 1 |a Wan, Gang  |e verfasserin  |4 aut 
700 1 |a Fu, Rong  |e verfasserin  |4 aut 
700 1 |a Huang, Hongling  |e verfasserin  |4 aut 
700 1 |a Sun, Xueyan  |e verfasserin  |4 aut 
700 1 |a Lee, Sang-Jun  |e verfasserin  |4 aut 
700 1 |a Lee, Jun-Sik  |e verfasserin  |4 aut 
700 1 |a Nordlund, Dennis  |e verfasserin  |4 aut 
700 1 |a Pianetta, Piero  |e verfasserin  |4 aut 
700 1 |a Zhao, Kejie  |e verfasserin  |4 aut 
700 1 |a Liu, Yijin  |e verfasserin  |4 aut 
700 1 |a Qiu, Jieshan  |e verfasserin  |4 aut 
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773 1 8 |g volume:33  |g year:2021  |g number:2  |g day:07  |g month:01  |g pages:e2006147 
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