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231225s2021 xx |||||o 00| ||eng c |
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|a 10.1002/adma.202006147
|2 doi
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|a pubmed24n1061.xml
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|a (DE-627)NLM318364387
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|a (NLM)33270282
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|a DE-627
|b ger
|c DE-627
|e rakwb
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|a eng
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|a Li, Shaofeng
|e verfasserin
|4 aut
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|a Operando Tailoring of Defects and Strains in Corrugated β-Ni(OH)2 Nanosheets for Stable and High-Rate Energy Storage
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|c 2021
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
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|2 rdacarrier
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|a Date Revised 12.01.2021
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a © 2020 Wiley-VCH GmbH.
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|a Nickel hydroxide represents a technologically important material for energy storage, such as hybrid supercapacitors. It has two different crystallographic polymorphs, α- and β-Ni(OH)2 , showing advantages in either theoretical capacity or cycling/rate performance, manifesting a trade-off trend that needs to be optimized for practical applications. Here, the synergistic superiorities in both activity and stability of corrugated β-Ni(OH)2 nanosheets are demonstrated through an electrochemical abuse approach. With ≈91% capacity retention after 10 000 cycles, the corrugated β-Ni(OH)2 nanosheets can deliver a gravimetric capacity of 457 C g-1 at a high current density of 30 A g-1 , which is nearly two and four times that of the regular α- and β-Ni(OH)2 , respectively. Operando spectroscopy and finite element analysis reveal that greatly enhanced chemical activity and structural robustness can be attributed to the in situ tailored lattice defects and the strain-induced highly curved micromorphology. This work demonstrates a multi-scale defect-and-strain co-design strategy, which is helpful for rational design and tuned fabrication of next-generation electrode materials for stable and high-rate energy storage
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|a Journal Article
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|a defects
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|a strain
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|a supercapacitors
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|a β-Ni(OH)2
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|a Sharma, Nikhil
|e verfasserin
|4 aut
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|a Yu, Chang
|e verfasserin
|4 aut
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|a Zhang, Yan
|e verfasserin
|4 aut
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|a Wan, Gang
|e verfasserin
|4 aut
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|a Fu, Rong
|e verfasserin
|4 aut
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|a Huang, Hongling
|e verfasserin
|4 aut
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|a Sun, Xueyan
|e verfasserin
|4 aut
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|a Lee, Sang-Jun
|e verfasserin
|4 aut
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|a Lee, Jun-Sik
|e verfasserin
|4 aut
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|a Nordlund, Dennis
|e verfasserin
|4 aut
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|a Pianetta, Piero
|e verfasserin
|4 aut
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|a Zhao, Kejie
|e verfasserin
|4 aut
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|a Liu, Yijin
|e verfasserin
|4 aut
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|a Qiu, Jieshan
|e verfasserin
|4 aut
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|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 33(2021), 2 vom: 07. Jan., Seite e2006147
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
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|g volume:33
|g year:2021
|g number:2
|g day:07
|g month:01
|g pages:e2006147
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|u http://dx.doi.org/10.1002/adma.202006147
|3 Volltext
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|d 33
|j 2021
|e 2
|b 07
|c 01
|h e2006147
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