Pickering Emulsion Transitions in 2,6-Lutidine Plus Water Critical Liquid Mixtures
Silica particle (S) stabilized oil-in-water Pickering emulsions are observed in the two-phase region of the critical liquid mixture 2,6-lutidine (L) plus water (W). De-emulsification is found at temperatures below a particle wetting transition temperature Tw(R) where Tw(R) decreases toward the lower...
| Veröffentlicht in: | Langmuir : the ACS journal of surfaces and colloids. - 1992. - 36(2020), 42 vom: 27. Okt., Seite 12601-12606 |
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| Weitere Verfasser: | , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2020
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| Zugriff auf das übergeordnete Werk: | Langmuir : the ACS journal of surfaces and colloids |
| Schlagworte: | Journal Article |
| Zusammenfassung: | Silica particle (S) stabilized oil-in-water Pickering emulsions are observed in the two-phase region of the critical liquid mixture 2,6-lutidine (L) plus water (W). De-emulsification is found at temperatures below a particle wetting transition temperature Tw(R) where Tw(R) decreases toward the lower critical temperature Tc for smaller particle radii R. The presence of a Pickering emulsion transition and its dependence upon particle radius can be explained by a competition between destabilizing gravitational forces and stabilizing forces originating from the critical interfacial tension. As a corollary to these observations, the line tension τ at the three-phase SLW contact line is determined as a function of temperature |
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| Beschreibung: | Date Revised 27.10.2020 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 1520-5827 |
| DOI: | 10.1021/acs.langmuir.0c02161 |