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231225s2020 xx |||||o 00| ||eng c |
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|a 10.1002/adma.202003592
|2 doi
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|a pubmed24n1052.xml
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|a DE-627
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|e rakwb
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|a eng
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|a Yang, Xin
|e verfasserin
|4 aut
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|a Mass-Producible, Quasi-Zero-Strain, Lattice-Water-Rich Inorganic Open-Frameworks for Ultrafast-Charging and Long-Cycling Zinc-Ion Batteries
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|c 2020
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|a Text
|b txt
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|a ƒaComputermedien
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|a ƒa Online-Ressource
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|a Date Revised 10.11.2020
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a © 2020 Wiley-VCH GmbH.
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|a Low-cost and high-safety aqueous Zn-ion batteries are an exceptionally compelling technology for grid-scale energy storage. However, their development has been plagued by the lack of stable cathode materials allowing fast Zn2+ -ion insertion and scalable synthesis. Here, a lattice-water-rich, inorganic-open-framework (IOF) phosphovanadate cathode, which is mass-producible and delivers high capacity (228 mAh g-1 ) and energy density (193.8 Wh kg-1 or 513 Wh L-1 ), is reported. The abundant lattice waters functioning as a "charge shield" enable a low Zn2+ -migration energy barrier, (0.66 eV) even close to that of Li+ within LiFePO4 . This fast intrinsic ion-diffusion kinetics, together with nanostructure effect, allow the achievements of ultrafast charging (71% state of charge in 1.9 min) and an ultrahigh power density (7200 W kg-1 at 107 Wh kg-1 ). Equally important, the IOF exhibits a quasi-zero-strain feature (<1% lattice change upon (de)zincation), which ensures ultrahigh cycling durability (3000 cycles) and Coulombic efficiencies of 100%. The cell-level energy and power densities reach ≈90 Wh kg-1 and ≈3320 W kg-1 , far surpassing commercial lead-acid, Ni-Cd, and Ni-MH batteries. Lattice-water-rich IOFs may open up new opportunities for exploring stable and fast-charging Zn-ion batteries
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|a Journal Article
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|a cathodes
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|a inorganic open-framework
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|a ultrafast charging
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|a zero-strain
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|a zinc-ion batteries
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|a Deng, Wenzhuo
|e verfasserin
|4 aut
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|a Chen, Ming
|e verfasserin
|4 aut
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|a Wang, Yaobing
|e verfasserin
|4 aut
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|a Sun, Chuan-Fu
|e verfasserin
|4 aut
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|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 32(2020), 45 vom: 18. Nov., Seite e2003592
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
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|g volume:32
|g year:2020
|g number:45
|g day:18
|g month:11
|g pages:e2003592
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|u http://dx.doi.org/10.1002/adma.202003592
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