Reuse of ammonium sulfate double salt crystals formed during electrolytic manganese production

Ammonium sulfate double salt crystals (ASDSCs) are formed during the electrolytic production of manganese. Typically, the large volume of ASDSCs accumulates in the open air, and this leads to serious environmental pollution and wastage of resources. In this study, we developed a new double-membrane...

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Veröffentlicht in:Water science and technology : a journal of the International Association on Water Pollution Research. - 1986. - 82(2020), 4 vom: 24. Aug., Seite 615-626
1. Verfasser: Zhang, Shaobo (VerfasserIn)
Weitere Verfasser: Wang, Sanfan, Zhang, Qianqian, Li, Yanhong, Xing, Yue, Ren, Guangyi
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2020
Zugriff auf das übergeordnete Werk:Water science and technology : a journal of the International Association on Water Pollution Research
Schlagworte:Journal Article Ammonium Compounds Manganese 42Z2K6ZL8P Ammonia 7664-41-7 Ammonium Sulfate SU46BAM238
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520 |a Ammonium sulfate double salt crystals (ASDSCs) are formed during the electrolytic production of manganese. Typically, the large volume of ASDSCs accumulates in the open air, and this leads to serious environmental pollution and wastage of resources. In this study, we developed a new double-membrane three-chamber electrolysis method. In this method, ASDSCs were dissolved in water and then pretreated stepwise to precipitate manganese(II) carbonate and magnesium carbonate. These precipitates were filtered and the filtrate (mainly ammonium sulfate) was subjected to double-membrane three-chamber electrodecomposition to produce sulfuric acid and ammonia. Further investigations showed that under the optimal conditions of current density of 250 A/m2, electrolysis time of 18 h, and temperature of 40 °C, the decomposition rate of ammonium sulfate reached as high as 96.15%. Thus, using this method, ASDSCs can be completely decomposed, which resolves the problem of environmental pollution and provides certain economic benefits to enterprises 
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650 7 |a Ammonium Sulfate  |2 NLM 
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700 1 |a Wang, Sanfan  |e verfasserin  |4 aut 
700 1 |a Zhang, Qianqian  |e verfasserin  |4 aut 
700 1 |a Li, Yanhong  |e verfasserin  |4 aut 
700 1 |a Xing, Yue  |e verfasserin  |4 aut 
700 1 |a Ren, Guangyi  |e verfasserin  |4 aut 
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