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231225s2020 xx |||||o 00| ||eng c |
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|a 10.2166/wst.2020.351
|2 doi
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|a pubmed24n1051.xml
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|a (DE-627)NLM315319836
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|a (NLM)32960794
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|a DE-627
|b ger
|c DE-627
|e rakwb
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|a eng
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|a Wei, Jinyu
|e verfasserin
|4 aut
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|a In-situ synthesis of poly(m-phenylenediamine) on chitin bead for Cr(VI) removal
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|c 2020
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
|b cr
|2 rdacarrier
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|a Date Completed 25.09.2020
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|a Date Revised 15.12.2020
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|a published: Print
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|a Citation Status MEDLINE
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|a In this work, a user-friendly chitin-based adsorbent (CT-PmPD) was synthesized by in-situ polymerization of m-phenylenediamine on chitin bead, which could effectively remove Cr(VI) from water. The structure and morphology of the CT-PmPD were characterized by FT-IR, XRD, SEM, zeta potential and XPS. Specifically, the effect of adsorbed dosage, pH, contact time, adsorption temperature and coexisting salt on the adsorption of Cr(VI) were studied. Besides, the adsorption mechanism of CT-PmPD toward Cr(VI) were also analyzed. Consequently, CT-PmPD exhibited a monolayer adsorption and the Langmuir model fitted a Cr(VI) adsorption capacity reaching 185.4 mg/g at 298 K. The high adsorption capacity was attributed to the abundant amino groups of CT-PmPD, which could be protonated to boost the electrostatic attraction of Cr(VI) oxyanions, thus providing electron to reduce Cr(VI). Additionally, the CT-PmPD revealed a good regeneration and reusability capacity, maintaining most of its adsorption capacity even after five cycles of adsorption-desorption. This high adsorption capacity and excellent regeneration performance highlighted the great potential of CT-PmPD for the removal of Cr(VI)
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|a Journal Article
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|a Phenylenediamines
|2 NLM
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|a Water Pollutants, Chemical
|2 NLM
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|a poly(1,3-phenylenediamine)
|2 NLM
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|a Chromium
|2 NLM
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|a 0R0008Q3JB
|2 NLM
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|a Chitin
|2 NLM
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|a 1398-61-4
|2 NLM
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|a chromium hexavalent ion
|2 NLM
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|a 18540-29-9
|2 NLM
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|a 3-phenylenediamine
|2 NLM
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|a OE624J2447
|2 NLM
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1 |
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|a Hu, Huayu
|e verfasserin
|4 aut
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1 |
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|a Zhang, Yanjuan
|e verfasserin
|4 aut
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1 |
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|a Huang, Zuqiang
|e verfasserin
|4 aut
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|a Liang, Xingtang
|e verfasserin
|4 aut
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|a Yin, Yanzhen
|e verfasserin
|4 aut
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|i Enthalten in
|t Water science and technology : a journal of the International Association on Water Pollution Research
|d 1986
|g 82(2020), 3 vom: 22. Aug., Seite 492-502
|w (DE-627)NLM098149431
|x 0273-1223
|7 nnns
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|g volume:82
|g year:2020
|g number:3
|g day:22
|g month:08
|g pages:492-502
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|u http://dx.doi.org/10.2166/wst.2020.351
|3 Volltext
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|d 82
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|h 492-502
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