In-situ synthesis of poly(m-phenylenediamine) on chitin bead for Cr(VI) removal

In this work, a user-friendly chitin-based adsorbent (CT-PmPD) was synthesized by in-situ polymerization of m-phenylenediamine on chitin bead, which could effectively remove Cr(VI) from water. The structure and morphology of the CT-PmPD were characterized by FT-IR, XRD, SEM, zeta potential and XPS....

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Veröffentlicht in:Water science and technology : a journal of the International Association on Water Pollution Research. - 1986. - 82(2020), 3 vom: 22. Aug., Seite 492-502
1. Verfasser: Wei, Jinyu (VerfasserIn)
Weitere Verfasser: Hu, Huayu, Zhang, Yanjuan, Huang, Zuqiang, Liang, Xingtang, Yin, Yanzhen
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2020
Zugriff auf das übergeordnete Werk:Water science and technology : a journal of the International Association on Water Pollution Research
Schlagworte:Journal Article Phenylenediamines Water Pollutants, Chemical poly(1,3-phenylenediamine) Chromium 0R0008Q3JB Chitin 1398-61-4 chromium hexavalent ion 18540-29-9 mehr... 3-phenylenediamine OE624J2447
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520 |a In this work, a user-friendly chitin-based adsorbent (CT-PmPD) was synthesized by in-situ polymerization of m-phenylenediamine on chitin bead, which could effectively remove Cr(VI) from water. The structure and morphology of the CT-PmPD were characterized by FT-IR, XRD, SEM, zeta potential and XPS. Specifically, the effect of adsorbed dosage, pH, contact time, adsorption temperature and coexisting salt on the adsorption of Cr(VI) were studied. Besides, the adsorption mechanism of CT-PmPD toward Cr(VI) were also analyzed. Consequently, CT-PmPD exhibited a monolayer adsorption and the Langmuir model fitted a Cr(VI) adsorption capacity reaching 185.4 mg/g at 298 K. The high adsorption capacity was attributed to the abundant amino groups of CT-PmPD, which could be protonated to boost the electrostatic attraction of Cr(VI) oxyanions, thus providing electron to reduce Cr(VI). Additionally, the CT-PmPD revealed a good regeneration and reusability capacity, maintaining most of its adsorption capacity even after five cycles of adsorption-desorption. This high adsorption capacity and excellent regeneration performance highlighted the great potential of CT-PmPD for the removal of Cr(VI) 
650 4 |a Journal Article 
650 7 |a Phenylenediamines  |2 NLM 
650 7 |a Water Pollutants, Chemical  |2 NLM 
650 7 |a poly(1,3-phenylenediamine)  |2 NLM 
650 7 |a Chromium  |2 NLM 
650 7 |a 0R0008Q3JB  |2 NLM 
650 7 |a Chitin  |2 NLM 
650 7 |a 1398-61-4  |2 NLM 
650 7 |a chromium hexavalent ion  |2 NLM 
650 7 |a 18540-29-9  |2 NLM 
650 7 |a 3-phenylenediamine  |2 NLM 
650 7 |a OE624J2447  |2 NLM 
700 1 |a Hu, Huayu  |e verfasserin  |4 aut 
700 1 |a Zhang, Yanjuan  |e verfasserin  |4 aut 
700 1 |a Huang, Zuqiang  |e verfasserin  |4 aut 
700 1 |a Liang, Xingtang  |e verfasserin  |4 aut 
700 1 |a Yin, Yanzhen  |e verfasserin  |4 aut 
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773 1 8 |g volume:82  |g year:2020  |g number:3  |g day:22  |g month:08  |g pages:492-502 
856 4 0 |u http://dx.doi.org/10.2166/wst.2020.351  |3 Volltext 
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