Photo-electrooxidation treatment of Acetaminophen in aqueous solution using BDD-Fe and BDD-Cu systems

In this study, acetaminophen (ACT) in aqueous solution was treated with electrooxidation and photo-electrooxidation processes (PEO). An electrochemical cell was used for the treatment of different concentrations of ACT (10, 50 and 80 mg L-1). A 23 factorial design was proposed, and the variables stu...

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Veröffentlicht in:Environmental technology. - 1993. - 43(2022), 8 vom: 15. März, Seite 1189-1199
1. Verfasser: Sierra-Sánchez, Ana Gabriela (VerfasserIn)
Weitere Verfasser: Linares-Hernández, Ivonne, Martínez-Miranda, Verónica, Almazán-Sánchez, Perla Tatiana, Teutli-Sequeira, Elia Alejandra, Castañeda-Juárez, Monserrat, Esparza-Soto, Mario
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2022
Zugriff auf das übergeordnete Werk:Environmental technology
Schlagworte:Journal Article Acetaminophen (ACT) BDD Electrooxidation UV light photo-electrooxidation Acetaminophen 362O9ITL9D Water Pollutants, Chemical
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520 |a In this study, acetaminophen (ACT) in aqueous solution was treated with electrooxidation and photo-electrooxidation processes (PEO). An electrochemical cell was used for the treatment of different concentrations of ACT (10, 50 and 80 mg L-1). A 23 factorial design was proposed, and the variables studied were current intensity 0.5 A (45.45 mA cm-2) and 1.0 A (90.91 mA cm-2), electrode configuration (anode:BDD, cathode:Fe or Cu) and presence/absence of UV light; NaCl 0.043 M (2.5 g L-1) was used as supporting electrolyte, the initial pH was 5.5, and the treatment time was 3 h. The aqueous solutions were characterized before and after the treatment using infrared spectroscopy (FT-IR), Ultraviolet-visible spectroscopy (UV-Vis), chemical oxygen demand (COD), total organic carbon (TOC), total carbon (TC), and fluorescence spectroscopy. The optimal operating conditions using an initial ACT concentration of 80 mg L-1 were 1.0 A, BDD-Fe configuration and UV light (254 nm). The removal efficiencies were 100% of ACT and 82.75% of TOC after 15 min of treatment. At concentrations of 50 and 10 mg L-1, 77.16% and 50.29% of TOC were removed after 10 and 5 min of treatment, respectively. Finally, the kinetic study showed an increase in the rate constants when the UV light was applied 
650 4 |a Journal Article 
650 4 |a Acetaminophen (ACT) 
650 4 |a BDD 
650 4 |a Electrooxidation 
650 4 |a UV light 
650 4 |a photo-electrooxidation 
650 7 |a Acetaminophen  |2 NLM 
650 7 |a 362O9ITL9D  |2 NLM 
650 7 |a Water Pollutants, Chemical  |2 NLM 
700 1 |a Linares-Hernández, Ivonne  |e verfasserin  |4 aut 
700 1 |a Martínez-Miranda, Verónica  |e verfasserin  |4 aut 
700 1 |a Almazán-Sánchez, Perla Tatiana  |e verfasserin  |4 aut 
700 1 |a Teutli-Sequeira, Elia Alejandra  |e verfasserin  |4 aut 
700 1 |a Castañeda-Juárez, Monserrat  |e verfasserin  |4 aut 
700 1 |a Esparza-Soto, Mario  |e verfasserin  |4 aut 
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