CO2 Capture by 2-(Methylamino)pyridine Ligated Aluminum Alkyl Complexes
A set of novel, easily synthesized aluminum complexes, Al[κ2-N,N-2-(methylamino)pyridine]2R (R = Et, iBu) are reported. When subjected to 1 atm of CO2 pressure, each hemilabile pyridine arm dissociates and facilitates cooperative activation of the CO2 substrate reminiscent of a Frustrated Lewis Pair...
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Détails bibliographiques
| Publié dans: | European journal of inorganic chemistry. - 1998. - 2020(2020), 31 vom: 23. Aug., Seite 2958-2967
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| Auteur principal: |
Yokley, Timothy W
(Auteur) |
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| Autres auteurs: |
Tupkar, Hrishikesh,
Schley, Nathan D,
DeYonker, Nathan J,
Brewster, Timothy P |
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| Format: | Article en ligne
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| Langue: | English |
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| Publié: |
2020
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| Accès à la collection: | European journal of inorganic chemistry
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| Sujets: | Journal Article
Aluminum
Carbamate
Carbon dioxide
Frustrated Lewis pair
Insertion |
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