Phosphate recovery from water using cellulose enhanced magnesium carbonate pellets : Kinetics, isotherms, and desorption

Phosphorus is an essential and limited nutrient that is supplied by a depleting resource, mineral phosphate rock. Eutrophication is occurring in many water bodies which provides an opportunity to recover this nutrient from the water. One method of recovery is through adsorption; this study focused o...

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Veröffentlicht in:Chemical engineering journal (Lausanne, Switzerland : 1996). - 1999. - 352(2018) vom: 15. Nov., Seite 612-624
1. Verfasser: Martin, Elisabeth (VerfasserIn)
Weitere Verfasser: Lalley, Jacob, Wang, Wenhu, Nadagouda, Mallikarjuna N, Sahle-Demessie, Endalkachew, Chae, So-Ryong
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2018
Zugriff auf das übergeordnete Werk:Chemical engineering journal (Lausanne, Switzerland : 1996)
Schlagworte:Journal Article Adsorption Cellulose Kinetics and sorption isotherms Magnesium carbonate Phosphorus Recovery of phosphate from water
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520 |a Phosphorus is an essential and limited nutrient that is supplied by a depleting resource, mineral phosphate rock. Eutrophication is occurring in many water bodies which provides an opportunity to recover this nutrient from the water. One method of recovery is through adsorption; this study focused on fabricating a porous and granular adsorptive material for the removal and recovery of phosphate. Magnesium carbonate was combined with cellulose in varying weight ratios (0, 5, 10, 15, 20%) to synthesize pellets, which were then calcined to increase internal surface area. Physiochemical properties such as surface area, surface morphology, elemental composition, and crystal structure of the materials were characterized using Brunauer, Emmett, and Teller (BET) surface area analysis, X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDS). The pellet proved to be uniform in composition and an increase in BET surface area correlated with an increase in cellulose content until pellet stability was lost. Phosphate adsorption using the pellets was studied via batch kinetics and sorption isotherms. The pseudo-second-order kinetics model fits best suggesting that the adsorption occurring was chemisorption. The isotherm model that fit best was the Langmuir isotherm, which showed that the maximum equilibrium adsorption capacity increased with an increase in cellulose content between 10% and 20%. The average adsorption capacity achieved in the triplicate isotherm study was 96.4 mg g-1 for pellets synthesized with 15% cellulose. Overall, using cellulose and subsequent calcination created an additional internal surface area for adsorption of phosphate and suggested that granular materials can be modified for efficient removal and recovery of phosphate from water 
650 4 |a Journal Article 
650 4 |a Adsorption 
650 4 |a Cellulose 
650 4 |a Kinetics and sorption isotherms 
650 4 |a Magnesium carbonate 
650 4 |a Phosphorus 
650 4 |a Recovery of phosphate from water 
700 1 |a Lalley, Jacob  |e verfasserin  |4 aut 
700 1 |a Wang, Wenhu  |e verfasserin  |4 aut 
700 1 |a Nadagouda, Mallikarjuna N  |e verfasserin  |4 aut 
700 1 |a Sahle-Demessie, Endalkachew  |e verfasserin  |4 aut 
700 1 |a Chae, So-Ryong  |e verfasserin  |4 aut 
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