Hierarchically Hollow and Porous NiO/NiCo2O4 Nanoprisms Encapsulated in Graphene Oxide for Lithium Storage

Engineering materials nanostructures is key for developing renewable energy technologies for lithium-ion batteries (LIBs) but remains a long-term research challenge. In this paper, heterostructured NiO/NiCo2O4 nanoprisms with a hierarchically hollow cavity and porous framework are rationally designe...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 36(2020), 33 vom: 25. Aug., Seite 9668-9674
1. Verfasser: Wang, Yingying (VerfasserIn)
Weitere Verfasser: Wang, Yang, Lu, Longgang, Zhang, Bin, Wang, Chengxin, He, Bin, Wei, Ren, Xu, Dongdong, Hao, Qingli, Liu, Ben
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2020
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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520 |a Engineering materials nanostructures is key for developing renewable energy technologies for lithium-ion batteries (LIBs) but remains a long-term research challenge. In this paper, heterostructured NiO/NiCo2O4 nanoprisms with a hierarchically hollow cavity and porous framework are rationally designed and further encapsulated in graphene oxide (NiO/NiCo2O4GO) as a highly efficient anode nanomaterial for LIBs. Heterostructured NiO/NiCo2O4 hollow/porous nanoprisms are derived by the ionic exchange of Ni precursors with [Co(CN)6]3- (CoNi-metal-organic framework (MOF)) and then annealed under air. The encapsulation is achieved by fast assembly of GO and NiO/NiCo2O4. Thanks to hierarchically hollow and porous nanostructure, heterostructured NiO/NiCo2O4, and overcoated GO, the NiO/NiCo2O4 electrode shows excellent electrochemical performance toward lithium storage, disclosing a large rate capacity of 468 mA h g-1 at 3.0 A g-1 and a good capacity retention of 561 mA h g-1 at 1 A g-1 after 800 cycles. This work paves a facile ionic exchange method for the controllable construction of hierarchically hollow MOFs and their derived composite nanomaterials for various energy-related applications 
650 4 |a Journal Article 
700 1 |a Wang, Yang  |e verfasserin  |4 aut 
700 1 |a Lu, Longgang  |e verfasserin  |4 aut 
700 1 |a Zhang, Bin  |e verfasserin  |4 aut 
700 1 |a Wang, Chengxin  |e verfasserin  |4 aut 
700 1 |a He, Bin  |e verfasserin  |4 aut 
700 1 |a Wei, Ren  |e verfasserin  |4 aut 
700 1 |a Xu, Dongdong  |e verfasserin  |4 aut 
700 1 |a Hao, Qingli  |e verfasserin  |4 aut 
700 1 |a Liu, Ben  |e verfasserin  |4 aut 
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