An Enhanced Reduction-Adsorption Strategy for Cr(VI) : Fabrication and Application of L-Cysteine-doped Carbon@Polypyrrole with a Core/Shell Composite Structure

Reclamation and recycling of heavy metal ions can offer environmental protection and sustainable development. Here, we report the preparation of L-cysteine (L-cys)-doped glucose carbon sphere (GCS)polypyrrole (PPy) composites (GCS@PPy/L-cys). The adsorption performance and mechanism of GCS@PPy/L-cys...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1985. - 36(2020), 39 vom: 06. Okt., Seite 11508-11516
1. Verfasser: Li, Yinhui (VerfasserIn)
Weitere Verfasser: Peng, Longfei, Guo, Jun, Chen, Zan
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2020
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't
Beschreibung
Zusammenfassung:Reclamation and recycling of heavy metal ions can offer environmental protection and sustainable development. Here, we report the preparation of L-cysteine (L-cys)-doped glucose carbon sphere (GCS)polypyrrole (PPy) composites (GCS@PPy/L-cys). The adsorption performance and mechanism of GCS@PPy/L-cys toward Cr(VI) from water were investigated in detail. The chromate enrichment on GCS@PPy is significantly facilitated by doping with L-cys, which prevents the oxidative collapse of the structure. This approach leads to many reduction-adsorption sites that reduce the highly hazardous Cr(VI) into less toxic Cr(III). More significantly, the composite can be reused to fabricate supercapacitors that avoid secondary pollution. This strategy offers high-efficiency treatment and sustainable utilization of hypervalent metals in water
Beschreibung:Date Completed 20.10.2020
Date Revised 20.10.2020
published: Print-Electronic
Citation Status PubMed-not-MEDLINE
ISSN:1520-5827
DOI:10.1021/acs.langmuir.0c01849