An Enhanced Reduction-Adsorption Strategy for Cr(VI) : Fabrication and Application of L-Cysteine-doped Carbon@Polypyrrole with a Core/Shell Composite Structure
Reclamation and recycling of heavy metal ions can offer environmental protection and sustainable development. Here, we report the preparation of L-cysteine (L-cys)-doped glucose carbon sphere (GCS)polypyrrole (PPy) composites (GCS@PPy/L-cys). The adsorption performance and mechanism of GCS@PPy/L-cys...
Veröffentlicht in: | Langmuir : the ACS journal of surfaces and colloids. - 1985. - 36(2020), 39 vom: 06. Okt., Seite 11508-11516 |
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Weitere Verfasser: | , , |
Format: | Online-Aufsatz |
Sprache: | English |
Veröffentlicht: |
2020
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Zugriff auf das übergeordnete Werk: | Langmuir : the ACS journal of surfaces and colloids |
Schlagworte: | Journal Article Research Support, Non-U.S. Gov't |
Zusammenfassung: | Reclamation and recycling of heavy metal ions can offer environmental protection and sustainable development. Here, we report the preparation of L-cysteine (L-cys)-doped glucose carbon sphere (GCS)polypyrrole (PPy) composites (GCS@PPy/L-cys). The adsorption performance and mechanism of GCS@PPy/L-cys toward Cr(VI) from water were investigated in detail. The chromate enrichment on GCS@PPy is significantly facilitated by doping with L-cys, which prevents the oxidative collapse of the structure. This approach leads to many reduction-adsorption sites that reduce the highly hazardous Cr(VI) into less toxic Cr(III). More significantly, the composite can be reused to fabricate supercapacitors that avoid secondary pollution. This strategy offers high-efficiency treatment and sustainable utilization of hypervalent metals in water |
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Beschreibung: | Date Completed 20.10.2020 Date Revised 20.10.2020 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
ISSN: | 1520-5827 |
DOI: | 10.1021/acs.langmuir.0c01849 |