Large-Area Alignment of Supramolecular Columns by Photothermal Laser Writing

© 2020 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - 32(2020), 36 vom: 01. Sept., Seite e2002620
1. Verfasser: Park, Kangho (VerfasserIn)
Weitere Verfasser: Jin, Hyeong Min, Kwon, Kiok, Kim, Jang Hwan, Yun, Haeju, Han, Kyu Hyo, Yun, Taeyeong, Kim, Sang Ouk, Jung, Hee-Tae
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2020
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article directed self-assembly directional quenching laser writing orientation control supramolecules
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520 |a Controlling the orientation of highly periodic supramolecular structures of small feature size (<5 nm) is the first step for potential applications in optoelectronics, membranes, and template synthesis. A new method, namely, laser photothermal writing, is introduced to direct the orientation of supramolecular columns over a large area. Supramolecular columns consisting of taper-shaped molecules with long aliphatic tail groups are aligned by a thermal gradient, which is induced by exposing a near-infrared laser beam to a graphene photothermal conversion layer. Intriguingly, the orientation of the supramolecular columns can be controlled in a facile manner by varying the laser scanning velocity and power. In contrast to previous methodologies for aligning supramolecular structures, this laser photothermal mechanism allows the directional and continuous alignment of supramolecular structures over an arbitrary large area with the easy control of laser irradiation. Besides, the laser process also enables area-selective orientation of the supramolecular structures for device-oriented nanopatterning 
650 4 |a Journal Article 
650 4 |a directed self-assembly 
650 4 |a directional quenching 
650 4 |a laser writing 
650 4 |a orientation control 
650 4 |a supramolecules 
700 1 |a Jin, Hyeong Min  |e verfasserin  |4 aut 
700 1 |a Kwon, Kiok  |e verfasserin  |4 aut 
700 1 |a Kim, Jang Hwan  |e verfasserin  |4 aut 
700 1 |a Yun, Haeju  |e verfasserin  |4 aut 
700 1 |a Han, Kyu Hyo  |e verfasserin  |4 aut 
700 1 |a Yun, Taeyeong  |e verfasserin  |4 aut 
700 1 |a Kim, Sang Ouk  |e verfasserin  |4 aut 
700 1 |a Jung, Hee-Tae  |e verfasserin  |4 aut 
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773 1 8 |g volume:32  |g year:2020  |g number:36  |g day:01  |g month:09  |g pages:e2002620 
856 4 0 |u http://dx.doi.org/10.1002/adma.202002620  |3 Volltext 
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