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231225s2020 xx |||||o 00| ||eng c |
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|a 10.1021/acs.langmuir.0c01335
|2 doi
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|a pubmed24n1042.xml
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|a (DE-627)NLM312728336
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|a (NLM)32696647
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|a DE-627
|b ger
|c DE-627
|e rakwb
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| 041 |
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|a eng
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| 100 |
1 |
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|a Gaboreau, Stephane
|e verfasserin
|4 aut
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| 245 |
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|a Hydration Properties and Interlayer Organization in Synthetic C-S-H
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| 264 |
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|c 2020
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| 336 |
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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| 338 |
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|a ƒa Online-Ressource
|b cr
|2 rdacarrier
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|a Date Revised 18.08.2020
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a Water in calcium silicate hydrate (C-S-H) is one of the key parameters driving the macroscopic behavior of cement materials for which water vapor partial pressure has an impact on Young's modulus and the volumic properties. Several samples of C-S-H with a bulk Ca/Si ratio ranging between 0.6 and 1.6 were characterized to study their dehydration/hydration behavior under water-controlled conditions using29Si NMR, water adsorption volumetry, X-ray diffraction, and Fourier-transform near-infrared diffuse reflectance under various water pressures. Coherent with several previous studies, it was observed that an increase in the Ca/Si ratio is due to the progressive omission of Si bridging tetrahedra, with the resulting charge being compensated for by interlayer Ca, and that water conditioning influences the layer-to-layer distance and the achieved NMR spectral resolution. Water desorption experiments exhibit one step toward low relative pressure, accompanied by a decrease in the layer-to-layer distance. When sufficient energy is provided to the system (T ≥ 40 °C under vacuum) to remove the interlayer water, the shrinkage/swelling is partially reversible in our experimental conditions. A change in layer-to-layer distance of less than 3 Å is measured in the C-S-H between the wet and dried states. When the bridging SiO2 tetrahedra are omitted, interlayer Ca interacts with layer O and water interacts with the cations and potentially with the surfaces. This structural organization is interpreted as a mid-plane monolayer of water in the interlayer space, this latter accounting for about 30% of the volume of C-S-H particles
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|a Journal Article
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1 |
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|a Grangeon, Sylvain
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Claret, Francis
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Ihiawakrim, Dris
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Ersen, Ovidiu
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Montouillout, Valerie
|e verfasserin
|4 aut
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| 700 |
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|a Maubec, Nicolas
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Roosz, Cedric
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Henocq, Pierre
|e verfasserin
|4 aut
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| 700 |
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|a Carteret, Cédric
|e verfasserin
|4 aut
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| 773 |
0 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1999
|g 36(2020), 32 vom: 18. Aug., Seite 9449-9464
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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| 773 |
1 |
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|g volume:36
|g year:2020
|g number:32
|g day:18
|g month:08
|g pages:9449-9464
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|u http://dx.doi.org/10.1021/acs.langmuir.0c01335
|3 Volltext
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|h 9449-9464
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