|
|
|
|
| LEADER |
01000caa a22002652c 4500 |
| 001 |
NLM312335210 |
| 003 |
DE-627 |
| 005 |
20250227142131.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
231225s2020 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1002/adma.202002910
|2 doi
|
| 028 |
5 |
2 |
|a pubmed25n1040.xml
|
| 035 |
|
|
|a (DE-627)NLM312335210
|
| 035 |
|
|
|a (NLM)32656812
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Zhang, Tianjun
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Single-Atom Catalysts Supported by Crystalline Porous Materials
|b Views from the Inside
|
| 264 |
|
1 |
|c 2020
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Revised 03.11.2020
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a © 2020 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
|
| 520 |
|
|
|a Single-atom catalysts (SACs) have recently emerged as an exciting system in heterogeneous catalysis showing outstanding performance in many catalytic reactions. Single-atom catalytic sites alone are not stable and thus require stabilization from substrates. Crystalline porous materials such as zeolites and metal-organic frameworks (MOFs) are excellent substrates for SACs, offering high stability with the potential to further enhance their performance due to synergistic effects. This review features recent work on the structure, electronic, and catalytic properties of zeolite and MOF-protected SACs, offering atomic-scale views from the "inside" thanks to the subatomic resolution of synchrotron X-ray absorption spectroscopy (XAS). The extended X-ray absorption fine structure and associated methods will be shown to be powerful tools in identifying the single-atom site and can provide details into the coordination environment and bonding disorder of SACs. The X-ray absorption near-edge structure will be demonstrated as a valuable method in probing the electronic properties of SACs by analyzing the white line intensity, absorption edge shift, and pre-/postedge features. Emphasis is also placed on in situ/operando XAS using state-of-the-art equipment, which can unveil the changes in structure and properties of SACs during the dynamic catalytic processes in a highly sensitive and time-resolved manner
|
| 650 |
|
4 |
|a Journal Article
|
| 650 |
|
4 |
|a Review
|
| 650 |
|
4 |
|a X-ray absorption spectroscopy
|
| 650 |
|
4 |
|a catalysis
|
| 650 |
|
4 |
|a metal-organic frameworks
|
| 650 |
|
4 |
|a single-atom catalysts
|
| 650 |
|
4 |
|a zeolites
|
| 700 |
1 |
|
|a Chen, Ziyi
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Walsh, Andrew G
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Li, Yi
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Zhang, Peng
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 32(2020), 44 vom: 05. Nov., Seite e2002910
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnas
|
| 773 |
1 |
8 |
|g volume:32
|g year:2020
|g number:44
|g day:05
|g month:11
|g pages:e2002910
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1002/adma.202002910
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_350
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 32
|j 2020
|e 44
|b 05
|c 11
|h e2002910
|