2D Inorganic Bimolecular Crystals with Strong In-Plane Anisotropy for Second-Order Nonlinear Optics

© 2020 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - 32(2020), 32 vom: 28. Aug., Seite e2003146
1. Verfasser: Feng, Xin (VerfasserIn)
Weitere Verfasser: Sun, Zongdong, Pei, Ke, Han, Wei, Wang, Fakun, Luo, Peng, Su, Jianwei, Zuo, Nian, Liu, Guiheng, Li, Huiqiao, Zhai, Tianyou
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2020
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article 2D inorganic molecular crystals SbI3·3S8 in-plane anisotropy second harmonic generation (SHG)
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520 |a 2D inorganic bimolecular crystals, consisting of two different inorganic molecules, are expected to possess novel physical and chemical properties due to the synergistic effect of the individual components. However, 2D inorganic bimolecular crystals remain unexploited because of the difficulties in preparation arising from non-typical layered structures and intricate intermolecular interactions. Here, the synthesis of 2D inorganic bimolecular crystal SbI3 ·3S8 nanobelts via a facile vertical microspacing sublimation strategy is reported. The as-synthesized SbI3 ·3S8 nanobelts exhibit strong in-plane anisotropy of phonon vibrations and intramolecular vibrations as well as show anisotropic light absorption with a high dichroism ratio of 3.9. Furthermore, it is revealed that the second harmonic generation intensity of SbI3 ·3S8 nanobelts is highly dependent on the excitation wavelength and crystallographic orientation. This work can inspire the growth of more 2D inorganic bimolecular crystals and excite potential applications for bimolecular optoelectronic devices 
650 4 |a Journal Article 
650 4 |a 2D inorganic molecular crystals 
650 4 |a SbI3·3S8 
650 4 |a in-plane anisotropy 
650 4 |a second harmonic generation (SHG) 
700 1 |a Sun, Zongdong  |e verfasserin  |4 aut 
700 1 |a Pei, Ke  |e verfasserin  |4 aut 
700 1 |a Han, Wei  |e verfasserin  |4 aut 
700 1 |a Wang, Fakun  |e verfasserin  |4 aut 
700 1 |a Luo, Peng  |e verfasserin  |4 aut 
700 1 |a Su, Jianwei  |e verfasserin  |4 aut 
700 1 |a Zuo, Nian  |e verfasserin  |4 aut 
700 1 |a Liu, Guiheng  |e verfasserin  |4 aut 
700 1 |a Li, Huiqiao  |e verfasserin  |4 aut 
700 1 |a Zhai, Tianyou  |e verfasserin  |4 aut 
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773 1 8 |g volume:32  |g year:2020  |g number:32  |g day:28  |g month:08  |g pages:e2003146 
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