|
|
|
|
| LEADER |
01000naa a22002652 4500 |
| 001 |
NLM311457835 |
| 003 |
DE-627 |
| 005 |
20231225142310.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
231225s2020 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1002/adma.202002333
|2 doi
|
| 028 |
5 |
2 |
|a pubmed24n1038.xml
|
| 035 |
|
|
|a (DE-627)NLM311457835
|
| 035 |
|
|
|a (NLM)32567159
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Jung, Eui Dae
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Multiply Charged Conjugated Polyelectrolytes as a Multifunctional Interlayer for Efficient and Scalable Perovskite Solar Cells
|
| 264 |
|
1 |
|c 2020
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Revised 16.11.2020
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a © 2020 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
|
| 520 |
|
|
|a A series of anionic conjugated polyelectrolytes (CPEs) is synthesized based on poly(fluorene-co-phenylene) by varying the side-chain ionic density from two to six per repeat units (MPS2-TMA, MPS4-TMA, and MPS6-TMA). The effect of MPS2, 4, 6-TMA as interlayers on top of a hole-extraction layer of poly(bis(4-phenyl)-2,4,6-trimethylphenylamine (PTAA) is investigated in inverted perovskite solar cells (PeSCs). Owing to the improved wettability of perovskites on hydrophobic PTAA with the CPEs, the PeSCs with CPE interlayers demonstrate a significantly enhanced device performance, with negligible device-to-device dependence relative to the reference PeSC without CPEs. By increasing the ionic density in the MPS-TMA interlayers, the wetting, interfacial defect passivation, and crystal growth of the perovskites are significantly improved without increasing the series resistance of the PeSCs. In particular, the open-circuit voltage increases from 1.06 V for the PeSC with MPS2-TMA to 1.11 V for the PeSC with MPS6-TMA. The trap densities of the PeSCs with MPS2,4,6-TMA are further analyzed using frequency-dependent capacitance measurements. Finally, a large-area (1 cm2 ) PeSC is successfully fabricated with MPS6-TMA, showing a power conversion efficiency of 18.38% with negligible hysteresis and a stable power output under light soaking for 60 s
|
| 650 |
|
4 |
|a Journal Article
|
| 650 |
|
4 |
|a conjugated polyelectrolytes
|
| 650 |
|
4 |
|a defect passivation
|
| 650 |
|
4 |
|a perovskites
|
| 650 |
|
4 |
|a scalability
|
| 650 |
|
4 |
|a solar cells
|
| 700 |
1 |
|
|a Harit, Amit Kumar
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Kim, Do Hui
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Jang, Chung Hyeon
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Park, Jong Hyun
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Cho, Shinuk
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Song, Myoung Hoon
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Woo, Han Young
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 32(2020), 30 vom: 03. Juli, Seite e2002333
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
|
| 773 |
1 |
8 |
|g volume:32
|g year:2020
|g number:30
|g day:03
|g month:07
|g pages:e2002333
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1002/adma.202002333
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_350
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 32
|j 2020
|e 30
|b 03
|c 07
|h e2002333
|