The removal of Zn2+, Pb2+, and As(V) ions by lime activated fly ash and valorization of the exhausted adsorbent

Copyright © 2018 Elsevier Ltd. All rights reserved.

Bibliographische Detailangaben
Veröffentlicht in:Waste management (New York, N.Y.). - 1999. - 78(2018) vom: 15. Aug., Seite 366-378
1. Verfasser: Karanac, Milica (VerfasserIn)
Weitere Verfasser: Đolić, Maja, Veljović, Đorđe, Rajaković-Ognjanović, Vladana, Veličković, Zlate, Pavićević, Vladimir, Marinković, Aleksandar
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2018
Zugriff auf das übergeordnete Werk:Waste management (New York, N.Y.)
Schlagworte:Journal Article (Re)valorization of waste material Chemical activation Construction material Fly ash/Ca(OH)(2)
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520 |a This study focuses on the use of raw fly ash (FA) and modified fly ash - activated by lime (MFA), as effective and low-cost adsorbents for the removal of heavy metals (Zn2+, Pb2+ and As(V)), followed by the revalorization of the exhausted adsorbent. The granulometric, elemental analysis, point of zero charge (pHPZC), radiochemical and structural characterization were conducted using X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET), scanning electron microscopy (SEM), Fourier transform infrared (FTIR) and gamma spectrometry techniques. The optimal conditions and key factors influencing the adsorption process were assessed using the response surface method (RSM). The adsorption capacity of the MFA adsorbent for Zn2+, Pb2+ and As(V) removal, calculated by the Langmuir model, was found to be 33.13, 26.06, and 29.71 mg g-1, respectively. The kinetic and thermodynamic parameters indicated that the adsorption process is spontaneous and endothermic. Due to their low desorption potential of the exhausted adsorbents, their effective reuse was established to be feasible. For this reason, the valorization of this material as an additive in construction materials was thereafter studied, where testing its toxicity leaching (TCLP) as well as the mechanical properties of construction material containing exhausted MFA confirmed its safe use. Hence, this study points to a possible "two-in-one" reuse of coal ash, initially as an adsorbent and later as an additive in a construction material 
650 4 |a Journal Article 
650 4 |a (Re)valorization of waste material 
650 4 |a Chemical activation 
650 4 |a Construction material 
650 4 |a Fly ash/Ca(OH)(2) 
700 1 |a Đolić, Maja  |e verfasserin  |4 aut 
700 1 |a Veljović, Đorđe  |e verfasserin  |4 aut 
700 1 |a Rajaković-Ognjanović, Vladana  |e verfasserin  |4 aut 
700 1 |a Veličković, Zlate  |e verfasserin  |4 aut 
700 1 |a Pavićević, Vladimir  |e verfasserin  |4 aut 
700 1 |a Marinković, Aleksandar  |e verfasserin  |4 aut 
773 0 8 |i Enthalten in  |t Waste management (New York, N.Y.)  |d 1999  |g 78(2018) vom: 15. Aug., Seite 366-378  |w (DE-627)NLM098197061  |x 1879-2456  |7 nnns 
773 1 8 |g volume:78  |g year:2018  |g day:15  |g month:08  |g pages:366-378 
856 4 0 |u http://dx.doi.org/10.1016/j.wasman.2018.05.052  |3 Volltext 
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