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231225s2020 xx |||||o 00| ||eng c |
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|a 10.1021/acs.langmuir.0c01169
|2 doi
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|a pubmed24n1037.xml
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|a DE-627
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|a eng
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| 100 |
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|a Li, Yaxing
|e verfasserin
|4 aut
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| 245 |
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|a Evaporation-Induced Crystallization of Surfactants in Sessile Multicomponent Droplets
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|c 2020
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
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|2 rdacarrier
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|a Date Revised 17.07.2021
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a Surfactants have been widely studied and used in controlling droplet evaporation. In this work, we observe and study the crystallization of sodium dodecyl sulfate (SDS) within an evaporating glycerol-water mixture droplet. The crystallization is induced by the preferential evaporation of water, which decreases the solubility of SDS in the mixture. As a consequence, the crystals shield the droplet surface and cease the evaporation. The universality of the evaporation characteristics for a range of droplet sizes is revealed by applying a diffusion model, extended by Raoult's law. To describe the nucleation and growth of the crystals, we employ the 2-dimensional crystallization model of Weinberg [J. Non-Cryst. Solids 1991, 134, 116]. The results of this model compare favorably to our experimental results. Our findings may inspire the community to reconsider the role of high concentration of surfactants in a multicomponent evaporation system
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|a Journal Article
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|a Salvator, Valentin
|e verfasserin
|4 aut
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|a Wijshoff, Herman
|e verfasserin
|4 aut
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| 700 |
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|a Versluis, Michel
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Lohse, Detlef
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 36(2020), 26 vom: 07. Juli, Seite 7545-7552
|w (DE-627)NLM098181009
|x 1520-5827
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|g volume:36
|g year:2020
|g number:26
|g day:07
|g month:07
|g pages:7545-7552
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|u http://dx.doi.org/10.1021/acs.langmuir.0c01169
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