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231225s2020 xx |||||o 00| ||eng c |
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|a 10.1021/acs.langmuir.0c01036
|2 doi
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|a pubmed24n1035.xml
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|a (DE-627)NLM310601355
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|a (NLM)32479728
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|a DE-627
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|e rakwb
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|a eng
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| 100 |
1 |
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|a Yamano, Tsukasa
|e verfasserin
|4 aut
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| 245 |
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|a Unique Self-Assembly of Sequence-Controlled Amino Acid Derived Vinyl Polymer with Gradient Thermoresponsiveness along a Chain
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|c 2020
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
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|2 rdacarrier
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|a Date Completed 21.06.2021
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|a Date Revised 21.06.2021
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|a published: Print-Electronic
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|a Citation Status MEDLINE
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|a A novel water-soluble amino acid derived vinyl polymer whose block sequence was designed to achieve a gradient thermoresponsiveness along a chain was accurately prepared through an ultrarapid reversible addition-fragmentation chain-transfer polymerization. The polymer exhibited unique temperature-regulated self-assembly in water, leading to multiple nanostructural transformations including disassembly-to-ordered and ordered-to-ordered transitions. The morphologies were drastically changed by heating the solution from 4 °C (soluble form) to 20 °C (spherical micelle) to 70 °C (vesicle). Moreover, such transitions exhibited hysteresis upon cooling, namely, from 70 °C (vesicle) to 20 °C (wormlike micelle) to 4 °C (soluble form). In this polymer system, the specific monomer sequence contributed to the self-assembly behavior. These findings provide significant insight into the design of new thermoresponsive nanomaterials with potential applications in biomedical chemistry
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|a Journal Article
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|a Research Support, Non-U.S. Gov't
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|a Amino Acids
|2 NLM
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|a Micelles
|2 NLM
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|a Polymers
|2 NLM
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|a Vinyl Compounds
|2 NLM
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|a Higashi, Nobuyuki
|e verfasserin
|4 aut
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|a Koga, Tomoyuki
|e verfasserin
|4 aut
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| 773 |
0 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 36(2020), 23 vom: 16. Juni, Seite 6550-6556
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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| 773 |
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|g volume:36
|g year:2020
|g number:23
|g day:16
|g month:06
|g pages:6550-6556
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|u http://dx.doi.org/10.1021/acs.langmuir.0c01036
|3 Volltext
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