Controlling Crystal Growth via an Autonomously Longitudinal Scaffold for Planar Perovskite Solar Cells

© 2020 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - 32(2020), 26 vom: 07. Juli, Seite e2000617
1. Verfasser: Duan, Xiaopeng (VerfasserIn)
Weitere Verfasser: Li, Xiang, Tan, Licheng, Huang, Zengqi, Yang, Jia, Liu, Gengling, Lin, Zhuojia, Chen, Yiwang
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2020
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article crystal growth flexible devices perovskite solar cells poly(methyl methacrylate) scaffolds sequential deposition
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520 |a Sequential deposition is certified as an effective technology to obtain high-performance perovskite solar cells (PVSCs), which can be derivatized into large-scale industrial production. However, dense lead iodide (PbI2 ) causes incomplete reaction and unsatisfactory solution utilization of perovskite in planar PVSCs without mesoporous titanium dioxide as a support. Here, a novel autonomously longitudinal scaffold constructed by the interspersion of in situ self-polymerized methyl methacrylate (sMMA) in PbI2 is introduced to fabricate efficient PVSCs with excellent flexural endurance and environmental adaptability. By this strategy perovskite solution can be confined within an organic scaffold with vertical crystal growth promoted, effectively inhibiting exciton accumulation and recombination at grain boundaries. Additionally, sMMA cross-linked perovskite network can release mechanical stress and occupy the main channels for ion migration and water/oxygen permeation to significantly improve operational stability, which opens up a new strategy for the commercial development of large-area PVSCs in flexible electronics 
650 4 |a Journal Article 
650 4 |a crystal growth 
650 4 |a flexible devices 
650 4 |a perovskite solar cells 
650 4 |a poly(methyl methacrylate) 
650 4 |a scaffolds 
650 4 |a sequential deposition 
700 1 |a Li, Xiang  |e verfasserin  |4 aut 
700 1 |a Tan, Licheng  |e verfasserin  |4 aut 
700 1 |a Huang, Zengqi  |e verfasserin  |4 aut 
700 1 |a Yang, Jia  |e verfasserin  |4 aut 
700 1 |a Liu, Gengling  |e verfasserin  |4 aut 
700 1 |a Lin, Zhuojia  |e verfasserin  |4 aut 
700 1 |a Chen, Yiwang  |e verfasserin  |4 aut 
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773 1 8 |g volume:32  |g year:2020  |g number:26  |g day:07  |g month:07  |g pages:e2000617 
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