|
|
|
|
| LEADER |
01000naa a22002652 4500 |
| 001 |
NLM310313899 |
| 003 |
DE-627 |
| 005 |
20231225135828.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
231225s2020 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1002/adma.202001906
|2 doi
|
| 028 |
5 |
2 |
|a pubmed24n1034.xml
|
| 035 |
|
|
|a (DE-627)NLM310313899
|
| 035 |
|
|
|a (NLM)32449221
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Ling, Xufeng
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Guanidinium-Assisted Surface Matrix Engineering for Highly Efficient Perovskite Quantum Dot Photovoltaics
|
| 264 |
|
1 |
|c 2020
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Revised 30.09.2020
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a © 2020 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
|
| 520 |
|
|
|a Metal halide perovskite quantum dots (Pe-QDs) are of great interest in new-generation photovoltaics (PVs). However, it remains challenging in the construction of conductive and intact Pe-QD films to maximize their functionality. Herein, a ligand-assisted surface matrix strategy to engineer the surface and packing states of Pe-QD solids is demonstrated by a mild thermal annealing treatment after ligand exchange processing (referred to as "LE-TA") triggered by guanidinium thiocyanate. The "LE-TA" method induces the formation of surface matrix on CsPbI3 QDs, which is dominated by the cationic guanidinium (GA+ ) rather than the SCN- , maintaining the intact cubic structure and facilitating interparticle electrical interaction of QD solids. Consequently, the GA-matrix-confined CsPbI3 QDs exhibit remarkably enhanced charge mobility and carrier diffusion length compared to control ones, leading to a champion power conversion efficiency of 15.21% when assembled in PVs, which is one of the highest among all Pe-QD solar cells. Additionally, the "LE-TA" method shows similar effects when applied to other Pe-QD PV systems like CsPbBr3 and FAPbI3 (FA = formamidinium), indicating its versatility in regulating the surfaces of various Pe-QDs. This work may afford new guidelines to construct electrically conductive and structurally intact Pe-QD solids for efficient optoelectronic devices
|
| 650 |
|
4 |
|a Journal Article
|
| 650 |
|
4 |
|a CsPbI3
|
| 650 |
|
4 |
|a guanidinium thiocyanate
|
| 650 |
|
4 |
|a ligand exchange
|
| 650 |
|
4 |
|a perovskite quantum dots
|
| 650 |
|
4 |
|a solar cells
|
| 700 |
1 |
|
|a Yuan, Jianyu
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Zhang, Xuliang
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Qian, Yuli
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Zakeeruddin, Shaik M
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Larson, Bryon W
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Zhao, Qian
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Shi, Junwei
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Yang, Jiacheng
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Ji, Kang
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Zhang, Yannan
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Wang, Yongjie
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Zhang, Chunyang
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Duhm, Steffen
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Luther, Joseph M
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Grätzel, Michael
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Ma, Wanli
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 32(2020), 26 vom: 30. Juli, Seite e2001906
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
|
| 773 |
1 |
8 |
|g volume:32
|g year:2020
|g number:26
|g day:30
|g month:07
|g pages:e2001906
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1002/adma.202001906
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_350
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 32
|j 2020
|e 26
|b 30
|c 07
|h e2001906
|