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231225s2020 xx |||||o 00| ||eng c |
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|a 10.1002/ejic.201901278
|2 doi
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|a eng
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| 100 |
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|a van Alten, Richt S
|e verfasserin
|4 aut
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|a (Electro-)chemical Splitting of Dinitrogen with a Rhenium Pincer Complex
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|c 2020
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|a Date Revised 28.09.2020
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a © 2020 The Authors. Published by Wiley‐VCH Verlag GmbH & Co. KGaA.
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|a The splitting of N2 into well-defined terminal nitride complexes is a key reaction for nitrogen fixation at ambient conditions. In continuation of our previous work on rhenium pincer mediated N2 splitting, nitrogen activation and cleavage upon (electro)chemical reduction of [ReCl2(L2)] {L2 = N(CHCHPtBu2)2 -} is reported. The electrochemical characterization of [ReCl2(L2)] and comparison with our previously reported platform [ReCl2(L1)] {L1 = N(CH2CH2PtBu2)2 -} provides mechanistic insight to rationalize the dependence of nitride yield on the reductant. Furthermore, the reactivity of N2 derived nitride complex [Re(N)Cl(L2)] with electrophiles is presented
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|a Journal Article
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|a Cyclic voltammetry
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|a Electrochemistry
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|a Nitrogen fixation
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|a Pincer complexes
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|a Rhenium
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|a Wätjen, Florian
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Demeshko, Serhiy
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Miller, Alexander J M
|e verfasserin
|4 aut
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|a Würtele, Christian
|e verfasserin
|4 aut
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|a Siewert, Inke
|e verfasserin
|4 aut
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| 700 |
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|a Schneider, Sven
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t European journal of inorganic chemistry
|d 1998
|g 2020(2020), 15-16 vom: 30. Apr., Seite 1402-1410
|w (DE-627)NLM098272756
|x 1434-1948
|7 nnns
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| 773 |
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|g volume:2020
|g year:2020
|g number:15-16
|g day:30
|g month:04
|g pages:1402-1410
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|u http://dx.doi.org/10.1002/ejic.201901278
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