Honeycomb RhI3 Flakes with High Environmental Stability for Optoelectronics

© 2020 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - 32(2020), 25 vom: 20. Juni, Seite e2001979
1. Verfasser: Wang, Fakun (VerfasserIn)
Weitere Verfasser: Zhang, Zhuang, Zhang, Yue, Nie, Anmin, Zhao, Wei, Wang, Dong, Huang, Fuqiang, Zhai, Tianyou
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2020
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article 2D materials RhI3 field-effect ttansistors photodetectors transition metal trihalides
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520 |a The emerging 2D layered transition metal trihalides (MX3 ) have attracted extremely high interest given their exceptional structural and physical properties. Continuing to extend the library of 2D MX3 is essential for exploring new physical phenomena and enabling new functionality. Herein, the optical and electrical properties and the photodetection behavior of atomically thin RhI3 flakes exfoliated from bulk crystals are reported. This compound exhibits superior air and thermal stability, as well as thickness-dependent bandgap from 1.1 (18L) to 1.4 eV (2L). Field-effect transistors based on the few-layer RhI3 flakes display n-type semiconducting behavior with competitive mobility of 2.5 cm2 V-1 s-1 and ON/OFF current ratio of 4 × 104 . Importantly, the outstanding responsivity of 11.5 A W-1 and high specific detectivity of 2 × 1010 Jones are recorded from the RhI3 photodetectors under 980 nm illumination at room temperature in air. These findings indicate a variety of potential applications of atomically thin RhI3 flakes in future 2D-material-based electronic and optoelectronic devices 
650 4 |a Journal Article 
650 4 |a 2D materials 
650 4 |a RhI3 
650 4 |a field-effect ttansistors 
650 4 |a photodetectors 
650 4 |a transition metal trihalides 
700 1 |a Zhang, Zhuang  |e verfasserin  |4 aut 
700 1 |a Zhang, Yue  |e verfasserin  |4 aut 
700 1 |a Nie, Anmin  |e verfasserin  |4 aut 
700 1 |a Zhao, Wei  |e verfasserin  |4 aut 
700 1 |a Wang, Dong  |e verfasserin  |4 aut 
700 1 |a Huang, Fuqiang  |e verfasserin  |4 aut 
700 1 |a Zhai, Tianyou  |e verfasserin  |4 aut 
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773 1 8 |g volume:32  |g year:2020  |g number:25  |g day:20  |g month:06  |g pages:e2001979 
856 4 0 |u http://dx.doi.org/10.1002/adma.202001979  |3 Volltext 
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