Degradation of diclofenac by Fe(II)-activated peracetic acid

In this study, peracetic acid (PAA) activated by Fe(II) was proposed to remove diclofenac (DCF) in polluted water. It was found that Fe(II)/PAA system could effectively remove DCF at neutral condition, which has a significant advantage over classical Fenton process. According to the result of scaven...

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Veröffentlicht in:Environmental technology. - 1993. - 42(2021), 27 vom: 21. Nov., Seite 4333-4341
1. Verfasser: Wang, Zhenran (VerfasserIn)
Weitere Verfasser: Shi, Hongle, Wang, Shixiang, Liu, Yiqing, Fu, Yongsheng
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2021
Zugriff auf das übergeordnete Werk:Environmental technology
Schlagworte:Journal Article Peracetic acid degradation pathway diclofenac ferrous ion radical species Ferrous Compounds Water Pollutants, Chemical Diclofenac 144O8QL0L1 mehr... Peracetic Acid I6KPI2E1HD
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520 |a In this study, peracetic acid (PAA) activated by Fe(II) was proposed to remove diclofenac (DCF) in polluted water. It was found that Fe(II)/PAA system could effectively remove DCF at neutral condition, which has a significant advantage over classical Fenton process. According to the result of scavenging experiment, both hydroxyl radical and peroxy radical were considered to be responsible for the degradation of DCF. The influence of several operational parameters including initial pH, Fe(II) dosage, PAA concentration and common water matrix on DCF removal were investigated. 80% DCF was removed at mild condition (pH 6-7) within 60 s, and its removal rate could be enhanced with the increase in Fe(II) dosage and PAA concentration. Presence of HCO3- and natural organic matter (NOM) was proved to have a significantly negative impact on DCF degradation. Four probable degradation pathways of DCF were proposed based on the detected reaction products, including hydroxylation, C-N bond cleavage, decarboxylation and dehydrogenation 
650 4 |a Journal Article 
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650 4 |a diclofenac 
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650 7 |a Water Pollutants, Chemical  |2 NLM 
650 7 |a Diclofenac  |2 NLM 
650 7 |a 144O8QL0L1  |2 NLM 
650 7 |a Peracetic Acid  |2 NLM 
650 7 |a I6KPI2E1HD  |2 NLM 
700 1 |a Shi, Hongle  |e verfasserin  |4 aut 
700 1 |a Wang, Shixiang  |e verfasserin  |4 aut 
700 1 |a Liu, Yiqing  |e verfasserin  |4 aut 
700 1 |a Fu, Yongsheng  |e verfasserin  |4 aut 
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