Self-Assembly Hydrothermal Synthesis of Silverton-Type Polyoxometalate-Based Photocatalysts for Enhanced Degradation

The synthesis of some complex polyoxometalates (POMs) is critical to develop potential photocatalysts with high catalytic activity and selectivity. Here, we address this challenge by a hydrothermal self-assembly route to obtain a novel POM-based Co4W6O21(OH)2·4H2O with a hierarchical microsphere str...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 36(2020), 16 vom: 28. Apr., Seite 4454-4464
1. Verfasser: Dong, Hongmei (VerfasserIn)
Weitere Verfasser: Li, Wenhui, Ou, Yingqing, Gao, Di, Yang, Yibin, Zhang, Yunhuai, Xiao, Peng
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2020
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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245 1 0 |a Self-Assembly Hydrothermal Synthesis of Silverton-Type Polyoxometalate-Based Photocatalysts for Enhanced Degradation 
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520 |a The synthesis of some complex polyoxometalates (POMs) is critical to develop potential photocatalysts with high catalytic activity and selectivity. Here, we address this challenge by a hydrothermal self-assembly route to obtain a novel POM-based Co4W6O21(OH)2·4H2O with a hierarchical microsphere structure. The Co4W6O21(OH)2·4H2O crystallizes in the cubic space group Im3̅ with cell parameters: a = b = c = 12.878 Å, α = β = γ = 90°, and Z = 4. The structure is further characterized by X-ray diffraction, X-ray photoelectron spectroscopy, UV-vis spectroscopy, thermogravimetric analysis, and Fourier transform infrared spectra. After depositing Ag2O nanoparticles on the 3D Co4W6O21(OH)2·4H2O microsphere by photochemical synthesis, the Co4W6O21(OH)2·4H2O/Ag2O heterojunction presents enhanced photocatalytic activity for RhB compared with P25 and pristine Ag2O. Moreover, we confirm the key role of holes for the Co4W6O21(OH)2·4H2O/Ag2O and put forward a possible mechanism for the photocatalytic degradation reaction 
650 4 |a Journal Article 
700 1 |a Li, Wenhui  |e verfasserin  |4 aut 
700 1 |a Ou, Yingqing  |e verfasserin  |4 aut 
700 1 |a Gao, Di  |e verfasserin  |4 aut 
700 1 |a Yang, Yibin  |e verfasserin  |4 aut 
700 1 |a Zhang, Yunhuai  |e verfasserin  |4 aut 
700 1 |a Xiao, Peng  |e verfasserin  |4 aut 
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