Enhanced removal of refractory pollutant from aniline aerofloat wastewater using combined vacuum ultraviolet and ozone (VUV/O3) process
Aerofloats, such as aniline aerofloat ((C6H5NH)2PSSH), are extensively employed for collection activities in wastewater particularly in cases where minerals are in flotation. Although this aniline aerofloat has efficient collection properties, they are ordinarily biologically persistent chemicals in...
| Veröffentlicht in: | Water science and technology : a journal of the International Association on Water Pollution Research. - 1986. - 80(2019), 12 vom: 03. Dez., Seite 2250-2259 |
|---|---|
| 1. Verfasser: | |
| Weitere Verfasser: | , , , , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2019
|
| Zugriff auf das übergeordnete Werk: | Water science and technology : a journal of the International Association on Water Pollution Research |
| Schlagworte: | Journal Article Aniline Compounds Environmental Pollutants Waste Water Water Pollutants, Chemical Ozone 66H7ZZK23N |
| Zusammenfassung: | Aerofloats, such as aniline aerofloat ((C6H5NH)2PSSH), are extensively employed for collection activities in wastewater particularly in cases where minerals are in flotation. Although this aniline aerofloat has efficient collection properties, they are ordinarily biologically persistent chemicals in which case their residual, as well as their byproducts, pose great environmental risks to water and soils. In this study, the removal efficiency of aniline aerofloat (AAF) by a combined vacuum ultraviolet (VUV) and ozone (O3) process (VUV/O3) was evaluated. Furthermore, the impacts of pH, O3, the concentration of AAF and coexisting ions (SiO32-, CO32-, Cl- (Na+), SO42-, Ca2+) were systematically studied. The experiments revealed that, with an initial AAF of 15 mg/L, AAF removal >88% was feasible with a reaction time of 60 min, pH of 8 and O3 of 6 g/h. The order of influence of the selected coexisting ions on the degradation of AAF by VUV/O3 was Ca2+ > CO32- > SiO32- > Cl- (Na+) >SO42-. Compared with VUV and O3 in terms of pollutant degradation rate, VUV/O3 showed a remarkable performance, followed by O3 and VUV. Additionally, the degradation kinetics of AAF by the VUV/O3 process agreed well with first-order elimination kinetics |
|---|---|
| Beschreibung: | Date Completed 07.04.2020 Date Revised 07.12.2022 published: Print Citation Status MEDLINE |
| ISSN: | 0273-1223 |
| DOI: | 10.2166/wst.2020.048 |