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231225s2020 xx |||||o 00| ||eng c |
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|a 10.1021/acs.langmuir.9b03223
|2 doi
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|a pubmed24n1027.xml
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|a eng
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1 |
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|a Teisala, Hannu
|e verfasserin
|4 aut
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|a Grafting Silicone at Room Temperature-a Transparent, Scratch-resistant Nonstick Molecular Coating
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|c 2020
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
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|a Date Revised 05.05.2020
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a Silicones are usually considered to be inert and, thus, not reactive with surfaces. Here we show that the most common silicone, methyl-terminated polydimethylsiloxane, spontaneously and stably bonds on glass-and any other material with silicon oxide surface chemistry-even at room temperature. As a result, a 2-5 nm thick and transparent coating, which shows extraordinary nonstick properties toward polar and nonpolar liquids, ice, and even super glue, is formed. Ten microliter drops of various liquids slide off a coated glass when the sample is inclined by less than 10°. Ice adhesion strength on a coated glass is only 2.7 ± 0.6 kPa, that is, more than 98% less than ice adhesion on an uncoated glass. The mechanically stable coating can be easily applied by painting, spraying, or roll-coating. Notably, the reaction does not require any excess energy or solvents, nor does it induce hazardous byproducts, which makes it an ideal option for environmentally sustainable surface modification in a myriad of technological applications
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|a Journal Article
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|a Baumli, Philipp
|e verfasserin
|4 aut
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|a Weber, Stefan A L
|e verfasserin
|4 aut
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|a Vollmer, Doris
|e verfasserin
|4 aut
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|a Butt, Hans-Jürgen
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 36(2020), 16 vom: 28. Apr., Seite 4416-4431
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|x 1520-5827
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| 773 |
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|g volume:36
|g year:2020
|g number:16
|g day:28
|g month:04
|g pages:4416-4431
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|u http://dx.doi.org/10.1021/acs.langmuir.9b03223
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