2D MXene-TiO2 Core-Shell Nanosheets as a Data-Storage Medium in Memory Devices

© 2020 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - 32(2020), 17 vom: 04. Apr., Seite e1907633
1. Verfasser: Lyu, Benzheng (VerfasserIn)
Weitere Verfasser: Choi, Yongsuk, Jing, Hongyue, Qian, Chuan, Kang, Hyunseok, Lee, Sungjoo, Cho, Jeong Ho
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2020
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article 2D MXenes MXene-TiO2 artificial synapses floating-gate memory window
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520 |a MXenes, an emerging class of 2D transition metal carbides and nitrides with the general formula Mn +1 Xn Tx (n = 1-4), have potential for application as floating gates in memory devices because of their intrinsic properties of a 2D structure, high density-of-states, and high work function. In this study, a series of MXene-TiO2 core-shell nanosheets are synthesized by deterministic control of the surface oxidation of MXene. The floating gate (multilayer MXene) and tunneling layer (TiO2 ) in a nano-floating-gate transistor memory (NFGTM) device are prepared simultaneously by a facile, low-cost, and water-based process. The memory performance is optimized via adjustment of the thickness of the oxidation layer formed on the MXene surface. The fabricated MXene NFGTMs exhibit excellent nonvolatile memory characteristics, including a large memory window (>35.2 V), high programming/erasing current ratio (≈106 ), low off-current (<1 pA), long retention (>104 s), and cyclic endurance (300 cycles). Furthermore, synaptic functions, including the excitatory postsynaptic current/inhibitory postsynaptic current, paired-pulse facilitation, and synaptic plasticity (long-term potentiation/depression), are successfully emulated using the MXene NFGTMs. The successful control of MXene oxidation and its application to NFGTMs are expected to inspire the application of MXene as a data-storage medium in future memory devices 
650 4 |a Journal Article 
650 4 |a 2D MXenes 
650 4 |a MXene-TiO2 
650 4 |a artificial synapses 
650 4 |a floating-gate 
650 4 |a memory window 
700 1 |a Choi, Yongsuk  |e verfasserin  |4 aut 
700 1 |a Jing, Hongyue  |e verfasserin  |4 aut 
700 1 |a Qian, Chuan  |e verfasserin  |4 aut 
700 1 |a Kang, Hyunseok  |e verfasserin  |4 aut 
700 1 |a Lee, Sungjoo  |e verfasserin  |4 aut 
700 1 |a Cho, Jeong Ho  |e verfasserin  |4 aut 
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773 1 8 |g volume:32  |g year:2020  |g number:17  |g day:04  |g month:04  |g pages:e1907633 
856 4 0 |u http://dx.doi.org/10.1002/adma.201907633  |3 Volltext 
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