New Brush Copolymers as an Effective Dispersant for Stabilizing Concentrated Suspensions of Silver Nanoparticles

Silver nanopowders (nano-Ag) have extremely high surface energy and are generally difficult to have an effective dispersant for their dispersion stabilization. This study proposes two brush copolymers that show a strong preference for adsorption on the nano-Ag surface via their backbone, while their...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 36(2020), 13 vom: 07. Apr., Seite 3377-3385
1. Verfasser: Chao, Tsung-Ming (VerfasserIn)
Weitere Verfasser: Hsieh, Ta-Li, Chang, Shinn-Jen, Chang, Cha-Wen, Li, Chia-Chen
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2020
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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520 |a Silver nanopowders (nano-Ag) have extremely high surface energy and are generally difficult to have an effective dispersant for their dispersion stabilization. This study proposes two brush copolymers that show a strong preference for adsorption on the nano-Ag surface via their backbone, while their side chains extend into the dispersion solvent for particle stabilization. After adding only 5 wt % (based on the mass of nano-Ag) of the proposed dispersants, the nano-Ag particles can be stably suspended without settling for at least 2 months. Besides, 5 wt % of these dispersants can well stabilize at least 40 wt % nano-Ag dispersed in di(ethylene glycol) ethyl ether, which is a common solvent for conductive inks and pastes. For applications, a thin film cast using the dispersed nano-Ag shows greatly improved surface flatness as compared to that made without the dispersant, and a low electrical resistivity of 2 × 10-5 Ω cm is obtained after the film is annealed at 170 °C for 20 min 
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700 1 |a Chang, Shinn-Jen  |e verfasserin  |4 aut 
700 1 |a Chang, Cha-Wen  |e verfasserin  |4 aut 
700 1 |a Li, Chia-Chen  |e verfasserin  |4 aut 
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