Enhanced Vertical Charge Transport of Homo- and Blended Semiconducting Polymers by Nanoconfinement

© 2020 The Authors. Published by WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Détails bibliographiques
Publié dans:Advanced materials (Deerfield Beach, Fla.). - 1998. - 32(2020), 10 vom: 09. März, Seite e1908087
Auteur principal: Ko, Jongkuk (Auteur)
Autres auteurs: Kim, Youngkeol, Kang, Jin Soo, Berger, Rüdiger, Yoon, Hyunsik, Char, Kookheon
Format: Article en ligne
Langue:English
Publié: 2020
Accès à la collection:Advanced materials (Deerfield Beach, Fla.)
Sujets:Journal Article conductive scanning force microscopy grazing incidence X-ray scattering nanoconfinement nanoimprint lithography nanopillars organic electronics
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520 |a The morphology of conjugated polymers has critical influences on electronic and optical properties of optoelectronic devices. Even though lots of techniques and methods are suggested to control the morphology of polymers, very few studies have been performed inducing high charge transport along out-of-plane direction. In this study, the self-assembly of homo- and blended conjugated polymers which are confined in nanostructures is utilized. The resulting structures lead to high charge mobility along vertical direction for both homo- and blended conjugated polymers. Both semicrystalline and amorphous polymers show highly increased population of face-on crystallite despite intrinsic crystallinity of polymers. They result in more than two orders of magnitude enhanced charge mobility along vertical direction revealed by nanoscale conductive scanning force microscopy and macroscale IV characteristic measurements. Moreover, blends of semicrystalline and amorphous polymers, which are known to show inferior optical and electrical properties due to their structural incompatibility, are formed into harmonious states by this approach. Assembly of blends of semicrystalline and amorphous polymers under nanoconfinement shows charge mobility in out-of-plane direction of 0.73 cm2 V-1 s-1 with wide range of absorption wavelength from 300 to 750 nm demonstrating the synergistic effects of two different polymers 
650 4 |a Journal Article 
650 4 |a conductive scanning force microscopy 
650 4 |a grazing incidence X-ray scattering 
650 4 |a nanoconfinement 
650 4 |a nanoimprint lithography 
650 4 |a nanopillars 
650 4 |a organic electronics 
700 1 |a Kim, Youngkeol  |e verfasserin  |4 aut 
700 1 |a Kang, Jin Soo  |e verfasserin  |4 aut 
700 1 |a Berger, Rüdiger  |e verfasserin  |4 aut 
700 1 |a Yoon, Hyunsik  |e verfasserin  |4 aut 
700 1 |a Char, Kookheon  |e verfasserin  |4 aut 
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