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231225s2020 xx |||||o 00| ||eng c |
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|a 10.1021/acs.langmuir.9b03297
|2 doi
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|a DE-627
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|a eng
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|a Vaillard, Anne-Sophie
|e verfasserin
|4 aut
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|a Confinement and Cross-Linking of 1,2-Polybutadiene in Two Dimensions at the Air-Water Interface
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|c 2020
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
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|2 rdacarrier
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|a Date Revised 12.02.2020
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|a published: Print-Electronic
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|a ErratumIn: Langmuir. 2020 Mar 17;36(10):2741. doi: 10.1021/acs.langmuir.0c00525. - PMID 32134678
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|a Citation Status PubMed-not-MEDLINE
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|a Langmuir monolayers of 1,2-polybutadiene (PB) were investigated by means of surface pressure-area isotherms, Brewster angle microscopy (BAM) observations, and sum-frequency generation (SFG) spectroscopy. A homogeneous and stable monolayer is formed 1.5 h after PB spreading provided that both light and oxygen are present. This was attributed to a slight oxidation of the PB at the air-water interface. The cross-linking of PB under UV photoirradiation was then studied. SFG spectroscopy demonstrates the in situ formation of a two-dimensional network. From surface pressure-area characterizations and BAM experiments, the cross-linked PB monolayer appears significantly denser and more rigid than the non-irradiated monolayer. Atomic force microscopy images reveal an increase by a factor of three in the root-mean-square roughness of the irradiated monolayers compared with the non-irradiated ones
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|a Journal Article
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|a El Haitami, Alae
|e verfasserin
|4 aut
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|a Dreier, Lisa B
|e verfasserin
|4 aut
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|a Backus, Ellen H G
|e verfasserin
|4 aut
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|a Cantin, Sophie
|e verfasserin
|4 aut
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1985
|g 36(2020), 4 vom: 04. Feb., Seite 862-871
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnas
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|g volume:36
|g year:2020
|g number:4
|g day:04
|g month:02
|g pages:862-871
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|u http://dx.doi.org/10.1021/acs.langmuir.9b03297
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