|
|
|
|
| LEADER |
01000caa a22002652c 4500 |
| 001 |
NLM304513962 |
| 003 |
DE-627 |
| 005 |
20250226104214.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
231225s2020 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1002/adma.201904987
|2 doi
|
| 028 |
5 |
2 |
|a pubmed25n1014.xml
|
| 035 |
|
|
|a (DE-627)NLM304513962
|
| 035 |
|
|
|a (NLM)31850607
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Tang, Kun
|e verfasserin
|4 aut
|
| 245 |
1 |
2 |
|a A Stable Solid Electrolyte Interphase for Magnesium Metal Anode Evolved from a Bulky Anion Lithium Salt
|
| 264 |
|
1 |
|c 2020
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Revised 30.09.2020
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a © 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
|
| 520 |
|
|
|a Rechargeable magnesium (Mg) metal batteries are a promising candidate for "post-Li-ion batteries" due to their high capacity, high abundance, and most importantly, highly reversible and dendrite-free Mg metal anode. However, the formation of passivating surface film rather than Mg2+ -conducting solid electrolyte interphase (SEI) on Mg anode surface has always restricted the development of rechargeable Mg batteries. A stable SEI is constructed on the surface of Mg metal anode by the partial decomposition of a pristine Li electrolyte in the electrochemical process. This Li electrolyte is easily prepared by dissolving lithium tetrakis(hexafluoroisopropyloxy)borate (Li[B(hfip)4 ]) in dimethoxyethane. It is noteworthy that Mg2+ can be directly introduced into this Li electrolyte during the initial electrochemical cycles for in situ forming a hybrid Mg2+ /Li+ electrolyte, and then the cycled electrolyte can conduct Mg-ion smoothly. The existence of this as-formed SEI blocks the further parasitic reaction of Mg metal anode with electrolyte and enables this electrolyte enduring long-term electrochemical cycles stably. This approach of constructing superior SEI on Mg anode surface and exploiting novel Mg electrolyte provides a new avenue for practical application of high-performance rechargeable Mg batteries
|
| 650 |
|
4 |
|a Journal Article
|
| 650 |
|
4 |
|a lithium tetrakis(hexafluoroisopropyloxy)borate
|
| 650 |
|
4 |
|a magnesium metal anodes
|
| 650 |
|
4 |
|a rechargeable magnesium batteries
|
| 650 |
|
4 |
|a solid electrolyte interphase
|
| 700 |
1 |
|
|a Du, Aobing
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Dong, Shanmu
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Cui, Zili
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Liu, Xin
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Lu, Chenglong
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Zhao, Jingwen
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Zhou, Xinhong
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Cui, Guanglei
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 32(2020), 6 vom: 12. Feb., Seite e1904987
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnas
|
| 773 |
1 |
8 |
|g volume:32
|g year:2020
|g number:6
|g day:12
|g month:02
|g pages:e1904987
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1002/adma.201904987
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_350
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 32
|j 2020
|e 6
|b 12
|c 02
|h e1904987
|