|
|
|
|
| LEADER |
01000naa a22002652 4500 |
| 001 |
NLM304101907 |
| 003 |
DE-627 |
| 005 |
20231225114245.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
231225s2020 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1002/adma.201905950
|2 doi
|
| 028 |
5 |
2 |
|a pubmed24n1013.xml
|
| 035 |
|
|
|a (DE-627)NLM304101907
|
| 035 |
|
|
|a (NLM)31808591
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Shen, Yajing
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Hierarchical Porous Organometallic Polymers Fabricated by Direct Knitting
|b Recyclable Single-Site Catalysts with Enhanced Activity
|
| 264 |
|
1 |
|c 2020
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Revised 30.09.2020
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a © 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
|
| 520 |
|
|
|a Porous organometallic polymers (POMPs) with hierarchical pore structures, high specific surface areas, and atomically dispersed metal (Ir, Pd, Ru) centers are successfully fabricated by a facile one-pot method through direct knitting of diverse N-heterocyclic carbene metal (NHC-M) complexes. These polymers can function as recyclable solid single-site catalysts and exhibit excellent catalytic activity and selectivity in both dehydrogenation and hydrogenation reactions even at ppm-level catalyst loadings. Remarkably, a record turnover number (TON) of 1.01 × 106 is achieved in the hydrogenation of levulinic acid to γ-valerolactone, which is 750 times higher than that attained with corresponding bis-NHC-Ir complex
|
| 650 |
|
4 |
|a Journal Article
|
| 650 |
|
4 |
|a N-heterocyclic carbene metal complexes
|
| 650 |
|
4 |
|a biomass transformation
|
| 650 |
|
4 |
|a direct knitting
|
| 650 |
|
4 |
|a porous organometallic polymers
|
| 650 |
|
4 |
|a single-site catalysts
|
| 700 |
1 |
|
|a Zheng, Qingshu
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Zhu, Haibo
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Tu, Tao
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 32(2020), 6 vom: 06. Feb., Seite e1905950
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
|
| 773 |
1 |
8 |
|g volume:32
|g year:2020
|g number:6
|g day:06
|g month:02
|g pages:e1905950
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1002/adma.201905950
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_350
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 32
|j 2020
|e 6
|b 06
|c 02
|h e1905950
|