Combined Experimental and Theoretical Study of the Structure of AuPt Nanoparticles Prepared by Galvanic Exchange
In this article, experiment and theory are combined to analyze Pb and Cu underpotential deposition (UPD) on ∼1.7 nm Au nanoparticles (NPs) and the AuPt structures that result after galvanic exchange (GE) of the UPD layer for Pt. Experimental Pb (0.49 ML) and Pt (0.50 ML) coverages are close to value...
| Veröffentlicht in: | Langmuir : the ACS journal of surfaces and colloids. - 1992. - 35(2019), 50 vom: 17. Dez., Seite 16496-16507 |
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| Weitere Verfasser: | , , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2019
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| Zugriff auf das übergeordnete Werk: | Langmuir : the ACS journal of surfaces and colloids |
| Schlagworte: | Journal Article |
| Zusammenfassung: | In this article, experiment and theory are combined to analyze Pb and Cu underpotential deposition (UPD) on ∼1.7 nm Au nanoparticles (NPs) and the AuPt structures that result after galvanic exchange (GE) of the UPD layer for Pt. Experimental Pb (0.49 ML) and Pt (0.50 ML) coverages are close to values predicted by density functional theory-molecular dynamics (DFT-MD, 0.59 ML). DFT-MD reveals that the AuNPs spontaneously reconstruct from cuboctahedral to a (111)-like structure prior to UPD. In the case of Pb, this results in the random electrodeposition of Pb onto the Au surface. This mechanism is a consequence of opposing trends in Pb-Pb and Pb-Au coordination numbers as a function of Pb coverage. Cu UPD is more complex, and agreement between theory and experiment takes into account ligand effects (e.g., SO42- present as the electrolyte) and the electric double layer. Importantly, AuPt structures formed upon Pt GE are found to differ markedly depending on the UPD metal. Specifically, cyclic voltammetry indicates that the Pt coverage is ∼0.20 ML greater for Cu UPD/Pt GE (0.70 ML) than for Pb UPD/Pt GE (0.50 ML). This difference is corroborated by DFT-MD theoretical predictions. Finally, DFT-MD calculations predict the formation of surface alloy and coreshell structures for Pb UPD/Pt GE and Cu UPD/Pt GE, respectively |
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| Beschreibung: | Date Revised 04.03.2020 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 1520-5827 |
| DOI: | 10.1021/acs.langmuir.9b03192 |