Van der Waals Integrated Hybrid POM-Zirconia Flexible Belt-Like Superstructures
© 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
| Veröffentlicht in: | Advanced materials (Deerfield Beach, Fla.). - 1998. - 32(2020), 2 vom: 17. Jan., Seite e1906794 |
|---|---|
| 1. Verfasser: | |
| Weitere Verfasser: | , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2020
|
| Zugriff auf das übergeordnete Werk: | Advanced materials (Deerfield Beach, Fla.) |
| Schlagworte: | Journal Article Van der Waals hybrid materials polyoxometalates superstructures thioether oxidation |
| Zusammenfassung: | © 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. A facile one-step solvothermal approach to engineer a van der Waals integrated heteromaterial self-assembled superstructure composed of two structurally distinct species that is polyoxomolybdate and zirconia (POM-ZrO2 ) is reported. Nonclassical aggregation-based self-assembly process grows the superstructure. The introduced POM not only behaves as a catalytically active component of the hybrid structure but also imparts flexibility to the developed POM-ZrO2 superstructures. The material shows high performance toward oxygenation of thioethers as a result of its morphology, composition, and structure. This growing strategy may introduce a viable pathway to the rational design of Van der Waals integrated complex hybrid, catalytically active assemblies with potential applications in different fields |
|---|---|
| Beschreibung: | Date Completed 17.01.2020 Date Revised 01.10.2020 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 1521-4095 |
| DOI: | 10.1002/adma.201906794 |