Modifications to the Aryl Group of dppf-Ligated Ni σ‑Aryl Precatalysts : Impact on Speciation and Catalytic Activity in Suzuki-Miyaura Coupling Reactions

There is currently significant interest in the development of efficient nickel precatalysts for cross-coupling. In this work, 14 nickel(II) precatalysts of the form (dppf)Ni(aryl)(X) (dppf = 1,1'-bis(diphenylphosphino)-ferrocene, X = Cl, Br) were synthesized. In particular, both the electronic...

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Publié dans:	Organometallics. - 1998. - 37(2018), 21 vom: 12. Nov., Seite 3943-3955
Auteur principal:	Beromi, Megan Mohadjer (Auteur)
Autres auteurs:	Banerjee, Gourab, Brudvig, Gary W, Charboneau, David J, Hazari, Nilay, Lant, Hannah M C, Mercado, Brandon Q
Format:	Article en ligne
Langue:	English
Publié:	2018
Accès à la collection:	Organometallics
Sujets:	Journal Article