Coordination Polymer to Atomically Thin, Holey, Metal-Oxide Nanosheets for Tuning Band Alignment

Coordination Polymer to Atomically Thin, Holey, Metal-Oxide Nanosheets for Tuning Band Alignment

© 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - 31(2019), 52 vom: 13. Dez., Seite e1905288
1. Verfasser: Mofarah, Sajjad S (VerfasserIn)
Weitere Verfasser: Adabifiroozjaei, Esmaeil, Pardehkhorram, Raheleh, Assadi, M Hussein N, Hinterstein, Manuel, Yao, Yin, Liu, Xinhong, Ghasemian, Mohammad B, Kalantar-Zadeh, Kourosh, Mehmood, Rashid, Cazorla, Claudio, Shahmiri, Reza, Bahmanrokh, Ghazaleh, Bhattacharyya, Saroj, Spadaro, Maria Chiara, Arbiol, Jordi, Lim, Sean, Xu, Yuwen, Arandiyan, Hamidreza, Scott, Jason, Koshy, Pramod, Sorrell, Charles C
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2019
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article 2D materials band alignment heterostructures holey nanosheets metal-based coordination polymers
Beschreibung
Zusammenfassung:© 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Holey 2D metal oxides have shown great promise as functional materials for energy storage and catalysts. Despite impressive performance, their processing is challenged by the requirement of templates plus capping agents or high temperatures; these materials also exhibit excessive thicknesses and low yields. The present work reports a metal-based coordination polymer (MCP) strategy to synthesize polycrystalline, holey, metal oxide (MO) nanosheets with thicknesses as low as two-unit cells. The process involves rapid exfoliation of bulk-layered, MCPs (Ce-, Ti-, Zr-based) into atomically thin MCPs at room temperature, followed by transformation into holey 2D MOs upon the removal of organic linkers in aqueous solution. Further, this work represents an extra step for decorating the holey nanosheets using precursors of transition metals to engineer their band alignments, establishing a route to optimize their photocatalysis. The work introduces a simple, high-yield, room-temperature, and template-free approach to synthesize ultrathin holey nanosheets with high-level functionalities
Beschreibung:Date Completed 30.12.2019
Date Revised 30.09.2020
published: Print-Electronic
Citation Status PubMed-not-MEDLINE
ISSN:1521-4095
DOI:10.1002/adma.201905288