A 0D/3D Heterostructured All-Inorganic Halide Perovskite Solar Cell with High Performance and Enhanced Phase Stability
© 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
| Veröffentlicht in: | Advanced materials (Deerfield Beach, Fla.). - 1998. - 31(2019), 48 vom: 13. Nov., Seite e1904735 |
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| Weitere Verfasser: | , , , , , , , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2019
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| Zugriff auf das übergeordnete Werk: | Advanced materials (Deerfield Beach, Fla.) |
| Schlagworte: | Journal Article 0D/3D heterostructured high performance inorganic perovskite phase stability solar cell |
| Zusammenfassung: | © 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. Although organic-inorganic hybrid perovskite solar cells (PVSCs) have achieved dramatic improvement in device efficiency, their long-term stability remains a major concern prior to commercialization. To address this issue, extensive research efforts are dedicated to exploiting all-inorganic PVSCs by using cesium (Cs)-based perovskite materials, such as α-CsPbI3 . However, the black-phase CsPbI3 (cubic α-CsPbI3 and orthorhombic γ-CsPbI3 phases) is not stable at room temperature, and it tends to convert to the nonperovskite δ-CsPbI3 phase. Here, a simple yet effective approach is described to prepare stable black-phase CsPbI3 by forming a heterostructure comprising 0D Cs4 PbI6 and γ-CsPbI3 through tuning the stoichiometry of the precursors between CsI and PbI. Such heterostructure is manifested to enable the realization of a stable all-inorganic PVSC with a high power conversion efficiency of 16.39%. This work provides a new perspective for developing high-performance and stable all-inorganic PVSCs |
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| Beschreibung: | Date Completed 26.11.2019 Date Revised 30.09.2020 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 1521-4095 |
| DOI: | 10.1002/adma.201904735 |