Host-Guest Hybrid Redox Materials Self-Assembled from Polyoxometalates and Single-Walled Carbon Nanotubes

Host-Guest Hybrid Redox Materials Self-Assembled from Polyoxometalates and Single-Walled Carbon Nanotubes

© 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - 31(2019), 41 vom: 22. Okt., Seite e1904182
1. Verfasser: Jordan, Jack W (VerfasserIn)
Weitere Verfasser: Lowe, Grace A, McSweeney, Robert L, Stoppiello, Craig T, Lodge, Rhys W, Skowron, Stephen T, Biskupek, Johannes, Rance, Graham A, Kaiser, Ute, Walsh, Darren A, Newton, Graham N, Khlobystov, Andrei N
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2019
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article carbon nanotubes electrochemistry nanoconfinement polyoxometalates redox materials
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520 |a The development of next-generation molecular-electronic, electrocatalytic, and energy-storage systems depends on the availability of robust materials in which molecular charge-storage sites and conductive hosts are in intimate contact. It is shown here that electron transfer from single-walled carbon nanotubes (SWNTs) to polyoxometalate (POM) clusters results in the spontaneous formation of host-guest POMSWNT redox-active hybrid materials. The SWNTs can conduct charge to and from the encapsulated guest molecules, allowing electrical access to >90% of the encapsulated redox species. Furthermore, the SWNT hosts provide a physical barrier, protecting the POMs from chemical degradation during charging/discharging and facilitating efficient electron transfer throughout the composite, even in electrolytes that usually destroy POMs 
650 4 |a Journal Article 
650 4 |a carbon nanotubes 
650 4 |a electrochemistry 
650 4 |a nanoconfinement 
650 4 |a polyoxometalates 
650 4 |a redox materials 
700 1 |a Lowe, Grace A  |e verfasserin  |4 aut 
700 1 |a McSweeney, Robert L  |e verfasserin  |4 aut 
700 1 |a Stoppiello, Craig T  |e verfasserin  |4 aut 
700 1 |a Lodge, Rhys W  |e verfasserin  |4 aut 
700 1 |a Skowron, Stephen T  |e verfasserin  |4 aut 
700 1 |a Biskupek, Johannes  |e verfasserin  |4 aut 
700 1 |a Rance, Graham A  |e verfasserin  |4 aut 
700 1 |a Kaiser, Ute  |e verfasserin  |4 aut 
700 1 |a Walsh, Darren A  |e verfasserin  |4 aut 
700 1 |a Newton, Graham N  |e verfasserin  |4 aut 
700 1 |a Khlobystov, Andrei N  |e verfasserin  |4 aut 
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