Mechanism of Superlubricity Conversion with Polyalkylene Glycol Aqueous Solutions

In this study, ultralow friction coefficient (COF, μ < 0.01) was obtained through polyalkylene glycol (PAG) aqueous solutions with different molecular weights (MWs) ranging from 270 to 3930 g·mol-1 under ambient conditions. With the increase in the MWs of PAG molecules, the threshold concentratio...

Ausführliche Beschreibung

Bibliographische Detailangaben
Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 35(2019), 36 vom: 10. Sept., Seite 11784-11790
1. Verfasser: Liu, Wenrui (VerfasserIn)
Weitere Verfasser: Wang, Hongdong, Liu, Yuhong, Li, Jinjin, Erdemir, Ali, Luo, Jianbin
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2019
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
LEADER 01000naa a22002652 4500
001 NLM300425821
003 DE-627
005 20231225102510.0
007 cr uuu---uuuuu
008 231225s2019 xx |||||o 00| ||eng c
024 7 |a 10.1021/acs.langmuir.9b01857  |2 doi 
028 5 2 |a pubmed24n1001.xml 
035 |a (DE-627)NLM300425821 
035 |a (NLM)31432683 
040 |a DE-627  |b ger  |c DE-627  |e rakwb 
041 |a eng 
100 1 |a Liu, Wenrui  |e verfasserin  |4 aut 
245 1 0 |a Mechanism of Superlubricity Conversion with Polyalkylene Glycol Aqueous Solutions 
264 1 |c 2019 
336 |a Text  |b txt  |2 rdacontent 
337 |a ƒaComputermedien  |b c  |2 rdamedia 
338 |a ƒa Online-Ressource  |b cr  |2 rdacarrier 
500 |a Date Revised 23.09.2019 
500 |a published: Print-Electronic 
500 |a ErratumIn: Langmuir. 2019 Nov 26;35(47):15431-15432. - PMID 31714094 
500 |a Citation Status PubMed-not-MEDLINE 
520 |a In this study, ultralow friction coefficient (COF, μ < 0.01) was obtained through polyalkylene glycol (PAG) aqueous solutions with different molecular weights (MWs) ranging from 270 to 3930 g·mol-1 under ambient conditions. With the increase in the MWs of PAG molecules, the threshold concentration to obtain this type of superlubric behavior gradually changed from 90 to 60 wt %. This phenomenon was closely related to the interaction between PAG chains and water molecules and the state of chemical binding. In the superlubricity system, superior load-bearing capacity was achieved at optimal threshold concentrations of all PAG aqueous solutions wherein multilayered adsorption layers that consisted of fully hydrated PAG molecules were formed on the sliding solid surfaces. With respect to the concentration below the threshold value, the existence of a shearing layer was indicated to play a significant role. Thus, the synergetic effect of sufficient adsorption of molecules and the unique shear rheology of the PAG aqueous solution were essential to achieve superlubricity 
650 4 |a Journal Article 
700 1 |a Wang, Hongdong  |e verfasserin  |4 aut 
700 1 |a Liu, Yuhong  |e verfasserin  |4 aut 
700 1 |a Li, Jinjin  |e verfasserin  |4 aut 
700 1 |a Erdemir, Ali  |e verfasserin  |4 aut 
700 1 |a Luo, Jianbin  |e verfasserin  |4 aut 
773 0 8 |i Enthalten in  |t Langmuir : the ACS journal of surfaces and colloids  |d 1992  |g 35(2019), 36 vom: 10. Sept., Seite 11784-11790  |w (DE-627)NLM098181009  |x 1520-5827  |7 nnns 
773 1 8 |g volume:35  |g year:2019  |g number:36  |g day:10  |g month:09  |g pages:11784-11790 
856 4 0 |u http://dx.doi.org/10.1021/acs.langmuir.9b01857  |3 Volltext 
912 |a GBV_USEFLAG_A 
912 |a SYSFLAG_A 
912 |a GBV_NLM 
912 |a GBV_ILN_22 
912 |a GBV_ILN_350 
912 |a GBV_ILN_721 
951 |a AR 
952 |d 35  |j 2019  |e 36  |b 10  |c 09  |h 11784-11790