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231225s2019 xx |||||o 00| ||eng c |
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|a 10.1021/acs.langmuir.9b01747
|2 doi
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|a pubmed24n0998.xml
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|a DE-627
|b ger
|c DE-627
|e rakwb
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|a eng
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|a Ohno, Kohji
|e verfasserin
|4 aut
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|a Polymer-Brush-Decorated Graphene Oxide
|b Precision Synthesis and Liquid-Crystal Formation
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|c 2019
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
|b cr
|2 rdacarrier
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|a Date Revised 23.09.2019
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a Given the specificity of the structure and function of graphene oxide (GO), hybridization with a variety of compounds will further extend its applications. To that end, we examined a new method for introducing a polymer brush onto the GO surface. In this method, GO was surface-modified with 2-((3-((2-bromo-2-methylpropanoyl)oxy)propyl)thio)ethylamine hydrochloride, which is a newly synthesized compound that contains an initiating group for atom transfer radical polymerization (ATRP) and an amino group for reacting with the epoxy groups on the GO surface. The ATRP-initiator-functionalized GO was then used as a substrate for the surface-initiated ATRP of methyl methacrylate (MMA), which produced graft polymers of poly(MMA) (PMMA) with targeted molecular weights and narrow molecular weight distributions; the average graft density was ∼0.06 chains/nm2. Because of their high dispersibilities and structural anisotropies, the PMMA-brush-decorated GOs formed lyotropic liquid crystals in their suspensions. In addition, similar suspensions with relatively high hybrid concentrations exhibited structural color that depended on the concentration
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|a Journal Article
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|a Zhao, Chenzhou
|e verfasserin
|4 aut
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|a Nishina, Yuta
|e verfasserin
|4 aut
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1999
|g 35(2019), 33 vom: 20. Aug., Seite 10900-10909
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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|g volume:35
|g year:2019
|g number:33
|g day:20
|g month:08
|g pages:10900-10909
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|u http://dx.doi.org/10.1021/acs.langmuir.9b01747
|3 Volltext
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|d 35
|j 2019
|e 33
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|h 10900-10909
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