Hydrothermal process development for the treatment of crocidolite asbestos waste

The asbestos-containing waste management is a public health topic for countries which have used this mineral. Treatment of chrysotile (white asbestos), a phyllosilicate from serpentine, crocidolite (blue asbestos, first results on this kind of asbestos), one of the five asbestos varieties of amphibo...

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Veröffentlicht in:Waste management & research : the journal of the International Solid Wastes and Public Cleansing Association, ISWA. - 1991. - 37(2019), 9 vom: 03. Sept., Seite 914-924
1. Verfasser: Nzogo Metoule, C T (VerfasserIn)
Weitere Verfasser: Delaby, S, Ferrasse, J H, Boutin, O
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2019
Zugriff auf das übergeordnete Werk:Waste management & research : the journal of the International Solid Wastes and Public Cleansing Association, ISWA
Schlagworte:Journal Article Chrysotile asbestos-containing waste crocidolite hydrothermal treatment supercritical water Asbestos, Serpentine Asbestos, Crocidolite 12001-28-4 Asbestos 1332-21-4
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520 |a The asbestos-containing waste management is a public health topic for countries which have used this mineral. Treatment of chrysotile (white asbestos), a phyllosilicate from serpentine, crocidolite (blue asbestos, first results on this kind of asbestos), one of the five asbestos varieties of amphibole family and asbestos-containing waste conversion process is proposed by using hydrothermal treatment in supercritical water. All samples were treated in an Inconel Batch Reactor. The treatment durations range is from 1 to 6 hours, temperatures range is from 400°C to 750°C, mass concentration range is from 0.02 to 170 mg. mL-1 and pressures are higher than 23 MPa. Ultrapure water is used for sample preparation. This ultrapure water is used to monitor mineral leaching on the aqueous phase and to avoid particle cross-contamination. Transmission electron microscopy analyses were carried out to check the presence or not of asbestos phase. According to these analyses, the best conditions of conversion were 1 hour and 0.02 mg. mL-1 for chrysotile, 3 hours and 0.02 mg. mL-1 for crocidolite and 1 hour and 20 mg. mL-1 for asbestos-containing waste, at T = 750°C. Supercritical water conditions were maintained during the whole treatment. The X-ray diffraction showed that the main phases present after treatments were riebeckite and magnetite (crocidolite), forsterite and enstatite (chrysotile), and calcite, spurrite and gehlenite (asbestos-containing waste). Finally, a scanning electron microscopy analysis was performed to monitor morphological fibre change. The elongated structure, partially fragmented, was found in all samples 
650 4 |a Journal Article 
650 4 |a Chrysotile 
650 4 |a asbestos-containing waste 
650 4 |a crocidolite 
650 4 |a hydrothermal treatment 
650 4 |a supercritical water 
650 7 |a Asbestos, Serpentine  |2 NLM 
650 7 |a Asbestos, Crocidolite  |2 NLM 
650 7 |a 12001-28-4  |2 NLM 
650 7 |a Asbestos  |2 NLM 
650 7 |a 1332-21-4  |2 NLM 
700 1 |a Delaby, S  |e verfasserin  |4 aut 
700 1 |a Ferrasse, J H  |e verfasserin  |4 aut 
700 1 |a Boutin, O  |e verfasserin  |4 aut 
773 0 8 |i Enthalten in  |t Waste management & research : the journal of the International Solid Wastes and Public Cleansing Association, ISWA  |d 1991  |g 37(2019), 9 vom: 03. Sept., Seite 914-924  |w (DE-627)NLM098164791  |x 1096-3669  |7 nnns 
773 1 8 |g volume:37  |g year:2019  |g number:9  |g day:03  |g month:09  |g pages:914-924 
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