Thermodynamic modelling and optimization of oxy-reforming and oxy-steam reforming of biogas by RSM
In this study, a comparative thermodynamic equilibrium calculation of biogas oxy-reforming and oxy-steam reforming processes to produce syngas has been conducted by Aspen Plus simulation software. The effects of temperature (600-800°C), pressure (1-20 atm), and inlet O2/CH4 (0-1.0), H2O/CH4 (0-3.0),...
| Veröffentlicht in: | Environmental technology. - 1993. - 41(2020), 1 vom: 15. Jan., Seite 14-28 |
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| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2020
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| Zugriff auf das übergeordnete Werk: | Environmental technology |
| Schlagworte: | Journal Article Gibbs free energy minimization Hydrogen reforming processes response surface methodology syngas Biofuels Steam 7YNJ3PO35Z |
| Zusammenfassung: | In this study, a comparative thermodynamic equilibrium calculation of biogas oxy-reforming and oxy-steam reforming processes to produce syngas has been conducted by Aspen Plus simulation software. The effects of temperature (600-800°C), pressure (1-20 atm), and inlet O2/CH4 (0-1.0), H2O/CH4 (0-3.0), and CO2/CH4 (0.3-1.0) mole ratios on the equilibrium compositions of products were determined. The operation of the process was optimized using Gibbs free energy minimization method and statistical approach: response surface methodology (RSM). Optimum operating conditions CH4/CO2/O2 = 1:0.51:0.12 at 788°C and 1 atm for oxy-reforming and CH4/CO2/H2O/O2 = 1:0.63:0.19:0.07 at 780°C and 1 atm for oxy-steam reforming were obtained to reach maximum H2 yield, CH4 and CO2 conversions by minimizing carbon selectivity to produce syngas for methanol production |
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| Beschreibung: | Date Completed 09.12.2019 Date Revised 17.12.2019 published: Print-Electronic Citation Status MEDLINE |
| ISSN: | 1479-487X |
| DOI: | 10.1080/09593330.2019.1639828 |