Enabling Tailorable Optical Properties and Markedly Enhanced Stability of Perovskite Quantum Dots by Permanently Ligating with Polymer Hairs

© 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - 31(2019), 32 vom: 26. Aug., Seite e1901602
1. Verfasser: Yoon, Young Jun (VerfasserIn)
Weitere Verfasser: Chang, Yajing, Zhang, Shuguang, Zhang, Meng, Pan, Shuang, He, Yanjie, Lin, Chun Hao, Yu, Shengtao, Chen, Yihuang, Wang, Zewei, Ding, Yong, Jung, Jaehan, Thadhani, Naresh, Tsukruk, Vladimir V, Kang, Zhitao, Lin, Zhiqun
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2019
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article block copolymers nanoreactors perovskite quantum dots stability
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520 |a Instability of perovskite quantum dots (QDs) toward humidity remains one of the major obstacles for their long-term use in optoelectronic devices. Herein, a general amphiphilic star-like block copolymer nanoreactor strategy for in situ crafting a set of hairy perovskite QDs with precisely tunable size and exceptionally high water and colloidal stabilities is presented. The selective partition of precursors within the compartment occupied by inner hydrophilic blocks of star-like diblock copolymers imparts in situ formation of robust hairy perovskite QDs permanently ligated by outer hydrophobic blocks via coprecipitation in nonpolar solvent. These size- and composition-tunable perovskite QDs reveal impressive water and colloidal stabilities as the surface of QDs is intimately and permanently ligated by a layer of outer hydrophobic polymer hairs. More intriguingly, the readily alterable length of outer hydrophobic polymers renders the remarkable control over the stability enhancement of hairy perovskite QDs 
650 4 |a Journal Article 
650 4 |a block copolymers 
650 4 |a nanoreactors 
650 4 |a perovskite 
650 4 |a quantum dots 
650 4 |a stability 
700 1 |a Chang, Yajing  |e verfasserin  |4 aut 
700 1 |a Zhang, Shuguang  |e verfasserin  |4 aut 
700 1 |a Zhang, Meng  |e verfasserin  |4 aut 
700 1 |a Pan, Shuang  |e verfasserin  |4 aut 
700 1 |a He, Yanjie  |e verfasserin  |4 aut 
700 1 |a Lin, Chun Hao  |e verfasserin  |4 aut 
700 1 |a Yu, Shengtao  |e verfasserin  |4 aut 
700 1 |a Chen, Yihuang  |e verfasserin  |4 aut 
700 1 |a Wang, Zewei  |e verfasserin  |4 aut 
700 1 |a Ding, Yong  |e verfasserin  |4 aut 
700 1 |a Jung, Jaehan  |e verfasserin  |4 aut 
700 1 |a Thadhani, Naresh  |e verfasserin  |4 aut 
700 1 |a Tsukruk, Vladimir V  |e verfasserin  |4 aut 
700 1 |a Kang, Zhitao  |e verfasserin  |4 aut 
700 1 |a Lin, Zhiqun  |e verfasserin  |4 aut 
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