Competition and Cooperation among Different Attractive Forces in Solutions of Inorganic-Organic Hybrids Containing Macroionic Clusters

Hybrids composed of nanoscale inorganic clusters and organic ligands are ideal models for understanding the different attractive forces during the self-assembly processes of complex macromolecules in solution. The counterion-mediated attraction induced by electrostatic interaction from the large, hy...

Ausführliche Beschreibung

Bibliographische Detailangaben
Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 35(2019), 24 vom: 18. Juni, Seite 7603-7616
1. Verfasser: Luo, Jiancheng (VerfasserIn)
Weitere Verfasser: Liu, Tianbo
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2019
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
LEADER 01000naa a22002652 4500
001 NLM29735986X
003 DE-627
005 20231225091828.0
007 cr uuu---uuuuu
008 231225s2019 xx |||||o 00| ||eng c
024 7 |a 10.1021/acs.langmuir.9b00480  |2 doi 
028 5 2 |a pubmed24n0991.xml 
035 |a (DE-627)NLM29735986X 
035 |a (NLM)31117725 
040 |a DE-627  |b ger  |c DE-627  |e rakwb 
041 |a eng 
100 1 |a Luo, Jiancheng  |e verfasserin  |4 aut 
245 1 0 |a Competition and Cooperation among Different Attractive Forces in Solutions of Inorganic-Organic Hybrids Containing Macroionic Clusters 
264 1 |c 2019 
336 |a Text  |b txt  |2 rdacontent 
337 |a ƒaComputermedien  |b c  |2 rdamedia 
338 |a ƒa Online-Ressource  |b cr  |2 rdacarrier 
500 |a Date Revised 23.07.2019 
500 |a published: Print-Electronic 
500 |a Citation Status PubMed-not-MEDLINE 
520 |a Hybrids composed of nanoscale inorganic clusters and organic ligands are ideal models for understanding the different attractive forces during the self-assembly processes of complex macromolecules in solution. The counterion-mediated attraction induced by electrostatic interaction from the large, hydrophilic macroionic clusters can compete or cooperate with other types of attractive forces such as hydrophobic interactions, hydrogen bonding, π-π stacking, and cation-π interactions from the organic ligands, consequently determining the solution behaviors of the hybrid molecules including their self-assembly process and the final supramolecular structures. The incorporation of organic ligands also leads to interesting responsive behaviors to external stimuli. Through the manipulation of the hybrid composition, architecture, topology, and solution conditions (e.g., solvent polarity, pH, and temperature), versatile self-assembled morphologies can be achieved, providing new scientific opportunities and potential applications 
650 4 |a Journal Article 
700 1 |a Liu, Tianbo  |e verfasserin  |4 aut 
773 0 8 |i Enthalten in  |t Langmuir : the ACS journal of surfaces and colloids  |d 1992  |g 35(2019), 24 vom: 18. Juni, Seite 7603-7616  |w (DE-627)NLM098181009  |x 1520-5827  |7 nnns 
773 1 8 |g volume:35  |g year:2019  |g number:24  |g day:18  |g month:06  |g pages:7603-7616 
856 4 0 |u http://dx.doi.org/10.1021/acs.langmuir.9b00480  |3 Volltext 
912 |a GBV_USEFLAG_A 
912 |a SYSFLAG_A 
912 |a GBV_NLM 
912 |a GBV_ILN_22 
912 |a GBV_ILN_350 
912 |a GBV_ILN_721 
951 |a AR 
952 |d 35  |j 2019  |e 24  |b 18  |c 06  |h 7603-7616