Recovery of phosphate as struvite from low-temperature combustion sewage sludge ash (LTCA) by cation exchange

Copyright © 2019 Elsevier Ltd. All rights reserved.

Bibliographische Detailangaben
Veröffentlicht in:Waste management (New York, N.Y.). - 1999. - 90(2019) vom: 01. Mai, Seite 84-93
1. Verfasser: Meng, Xiangdong (VerfasserIn)
Weitere Verfasser: Liu, Xiaoji, Huang, Qunxing, Gao, Huaping, Tay, Kangrou, Yan, Jianhua
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2019
Zugriff auf das übergeordnete Werk:Waste management (New York, N.Y.)
Schlagworte:Journal Article Cation exchange bed Low-temperature combustion sludge ash Macroscopic parametric equation Thomas model Phosphorus recovery Struvite Cations Phosphates Sewage Phosphorus mehr... 27YLU75U4W AW3EJL1462
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520 |a Copyright © 2019 Elsevier Ltd. All rights reserved. 
520 |a As a phosphorus-rich material, low-temperature combustion sewage sludge ash (LTCA) contains over 9 wt% content of phosphorus (P) and a large proportion of impurities, especially the content of Fe arrives at 14.59 wt%. To fully utilize LTCA as a fertilizer, this study investigated a procedure for P recovery from LTCA via struvite crystallization with fewer impurities. The adsorption characteristics of P and Fe by cation exchange resin (CER) were explored by simulating using the macroscopic parametric equation Thomas model. Optimum purification conditions for P-rich leachate by cation exchange column method were determined. Results showed that approximately 97.21 wt% of P was extracted from LTCA at HCl concentration of 0.8 M and liquid/solid ratio of 20.0 ml/g. More than 90 wt% of impurities could be detached by making P-rich leachate flow through cation exchange bed filled by CER at 300 ml/h. The macroscopic parametric equation Thomas model could clearly describe the adsorption characteristics of Fe in P-rich leachate by CER. Theoretical basis for purification of high concentration Fe in P-rich leachate by CER was provided. Approximately 84.04 wt% of total P in LTCA was recovered as struvite crystal which had low concentrations of heavy metals (5.96 mg/kg for Cr, 45.21 mg/kg for Cu, 29.67 mg/kg for Ni, 2.24 mg/kg for Pb, and 290.6 mg/kg for Zn) and could be eco-friendly for agricultural application. X-ray diffraction and SEM-EDS analysis validated the formation of struvite 
650 4 |a Journal Article 
650 4 |a Cation exchange bed 
650 4 |a Low-temperature combustion sludge ash 
650 4 |a Macroscopic parametric equation Thomas model 
650 4 |a Phosphorus recovery 
650 4 |a Struvite 
650 7 |a Cations  |2 NLM 
650 7 |a Phosphates  |2 NLM 
650 7 |a Sewage  |2 NLM 
650 7 |a Phosphorus  |2 NLM 
650 7 |a 27YLU75U4W  |2 NLM 
650 7 |a Struvite  |2 NLM 
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700 1 |a Liu, Xiaoji  |e verfasserin  |4 aut 
700 1 |a Huang, Qunxing  |e verfasserin  |4 aut 
700 1 |a Gao, Huaping  |e verfasserin  |4 aut 
700 1 |a Tay, Kangrou  |e verfasserin  |4 aut 
700 1 |a Yan, Jianhua  |e verfasserin  |4 aut 
773 0 8 |i Enthalten in  |t Waste management (New York, N.Y.)  |d 1999  |g 90(2019) vom: 01. Mai, Seite 84-93  |w (DE-627)NLM098197061  |x 1879-2456  |7 nnas 
773 1 8 |g volume:90  |g year:2019  |g day:01  |g month:05  |g pages:84-93 
856 4 0 |u http://dx.doi.org/10.1016/j.wasman.2019.04.045  |3 Volltext 
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