Giant Enhancement in the Supercapacitance of NiFe-Graphene Nanocomposites Induced by a Magnetic Field

© 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - 31(2019), 28 vom: 17. Juli, Seite e1900189
1. Verfasser: Romero, Jorge (VerfasserIn)
Weitere Verfasser: Prima-Garcia, Helena, Varela, Maria, Miralles, Sara G, Oestreicher, Víctor, Abellán, Gonzalo, Coronado, Eugenio
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2019
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article magnetic materials metal segregation nanocomposites supercapacitors
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520 |a The rapid rise in energy demand in the past years has prompted a search for low-cost alternatives for energy storage, supercapacitors being one of the most important devices. It is shown that a dramatic enhancement (≈1100%, from 155 to 1850 F g-1 ) of the specific capacitance of a hybrid stimuli-responsive FeNi3 -graphene electrode material can be achieved when the charge/discharge cycling is performed in the presence of an applied magnetic field of 4000 G. This result is related to an unprecedented magnetic-field-induced metal segregation of the FeNi3 nanoparticles during the cycling, which results in the appearance of small Ni clusters (<5 nm) and, consequently, in an increase in pseudocapacitive sites. The results open the door to a systematic improvement of the capacitance values of hybrid supercapacitors, while moving the research in this area towards the development of magnetically addressable energy-storage devices 
650 4 |a Journal Article 
650 4 |a magnetic materials 
650 4 |a metal segregation 
650 4 |a nanocomposites 
650 4 |a supercapacitors 
700 1 |a Prima-Garcia, Helena  |e verfasserin  |4 aut 
700 1 |a Varela, Maria  |e verfasserin  |4 aut 
700 1 |a Miralles, Sara G  |e verfasserin  |4 aut 
700 1 |a Oestreicher, Víctor  |e verfasserin  |4 aut 
700 1 |a Abellán, Gonzalo  |e verfasserin  |4 aut 
700 1 |a Coronado, Eugenio  |e verfasserin  |4 aut 
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