|
|
|
|
| LEADER |
01000naa a22002652 4500 |
| 001 |
NLM296649600 |
| 003 |
DE-627 |
| 005 |
20231225090308.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
231225s2019 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1002/adma.201900060
|2 doi
|
| 028 |
5 |
2 |
|a pubmed24n0988.xml
|
| 035 |
|
|
|a (DE-627)NLM296649600
|
| 035 |
|
|
|a (NLM)31045288
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Lin, Baowei
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Birnessite Nanosheet Arrays with High K Content as a High-Capacity and Ultrastable Cathode for K-Ion Batteries
|
| 264 |
|
1 |
|c 2019
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Revised 30.09.2020
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a © 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
|
| 520 |
|
|
|a Potassium-ion batteries (PIBs) are one of the emerging energy-storage technologies due to the low cost of potassium and theoretically high energy density. However, the development of PIBs is hindered by the poor K+ transport kinetics and the structural instability of the cathode materials during K+ intercalation/deintercalation. In this work, birnessite nanosheet arrays with high K content (K0.77 MnO2 ⋅0.23H2 O) are prepared by "hydrothermal potassiation" as a potential cathode for PIBs, demonstrating ultrahigh reversible specific capacity of about 134 mAh g-1 at a current density of 100 mA g-1 , as well as great rate capability (77 mAh g-1 at 1000 mA g-1 ) and superior cycling stability (80.5% capacity retention after 1000 cycles at 1000 mA g-1 ). With the introduction of adequate K+ ions in the interlayer, the K-birnessite exhibits highly stabilized layered structure with highly reversible structure variation upon K+ intercalation/deintercalation. The practical feasibility of the K-birnessite cathode in PIBs is further demonstrated by constructing full cells with a hard-soft composite carbon anode. This study highlights effective K+ -intercalation for birnessite to achieve superior K-storage performance for PIBs, making it a general strategy for developing high-performance cathodes in rechargeable batteries beyond lithium-ion batteries
|
| 650 |
|
4 |
|a Journal Article
|
| 650 |
|
4 |
|a birnessite
|
| 650 |
|
4 |
|a cathode
|
| 650 |
|
4 |
|a high K content
|
| 650 |
|
4 |
|a potassium-ion battery
|
| 650 |
|
4 |
|a ultrahigh stability
|
| 700 |
1 |
|
|a Zhu, Xiaohui
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Fang, Lingzhe
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Liu, Xinyi
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Li, Shuang
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Zhai, Teng
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Xue, Liang
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Guo, Qiubo
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Xu, Jing
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Xia, Hui
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 31(2019), 24 vom: 15. Juni, Seite e1900060
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
|
| 773 |
1 |
8 |
|g volume:31
|g year:2019
|g number:24
|g day:15
|g month:06
|g pages:e1900060
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1002/adma.201900060
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_350
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 31
|j 2019
|e 24
|b 15
|c 06
|h e1900060
|