A Room-Temperature Ferroelectric Ferromagnet in a 1D Tetrahedral Chain Network
© 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Publié dans: | Advanced materials (Deerfield Beach, Fla.). - 1998. - 31(2019), 24 vom: 01. Juni, Seite e1808104 |
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Auteur principal: | |
Autres auteurs: | , , , , , , , , , , , , , , , , , , |
Format: | Article en ligne |
Langue: | English |
Publié: |
2019
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Accès à la collection: | Advanced materials (Deerfield Beach, Fla.) |
Sujets: | Journal Article 1D tetrahedral networks SrFeO2.5 ferroelectricity magnetoelectric coupling multiferroicity |
Résumé: | © 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. Ferroelectricity occurs in crystals with broken spatial inversion symmetry. In conventional perovskite oxides, concerted ionic displacements within a 3D network of transition-metal-oxygen polyhedra (MOx ) manifest spontaneous polarization. Meanwhile, some 2D networks of MOx foster geometric ferroelectricity with magnetism, owing to the distortion of the polyhedra. Because of the fundamentally different mechanism of ferroelectricity in a 2D network, one can further challenge an uncharted mechanism of ferroelectricity in a 1D channel of MOx and estimate its feasibility. Here, ferroelectricity and coupled ferromagnetism in a 1D FeO4 tetrahedral chain network of a brownmillerite SrFeO2.5 epitaxial thin film are presented. The result provides a new paradigm for designing low-dimensional MOx networks, which is expected to benefit the realization of macroscopic ferro-ordering materials including ferroelectric ferromagnets |
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Description: | Date Revised 01.10.2020 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
ISSN: | 1521-4095 |
DOI: | 10.1002/adma.201808104 |