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231225s2019 xx |||||o 00| ||eng c |
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|a 10.1002/adma.201900440
|2 doi
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|a pubmed24n0988.xml
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|a (NLM)31034119
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|a DE-627
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|e rakwb
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|a eng
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| 100 |
1 |
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|a Zou, Lianli
|e verfasserin
|4 aut
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| 245 |
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|a Fabrication of a Spherical Superstructure of Carbon Nanorods
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|c 2019
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
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|a Date Revised 01.10.2020
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a © 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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|a Hierarchical superstructures in nano/microsize have attracted great attention owing to their wide potential applications. Herein, a self-templated strategy is presented for the synthesis of a spherical superstructure of carbon nanorods (SS-CNR) in micrometers through the morphology-preserved thermal transformation of a spherical superstructure of metal-organic framework nanorods (SS-MOFNR). The self-ordered SS-MOFNR with a chestnut-shell-like superstructure composed of 1D MOF nanorods on the shell is synthesized by a hydrothermal transformation process from crystalline MOF nanoparticles. After carbonization in argon, the hierarchical SS-MOFNR transforms into SS-CNR, which preserves the original chestnut-shell-like superstructure with 1D porous carbon nanorods on the shell. Taking the advantage of this functional superstructure, SS-CNR immobilized with ultrafine palladium (Pd) nanoparticles (PdSS-CNR) exhibits excellent catalytic activity for formic acid dehydrogenation. This synthetic strategy provides a facile method to synthesize uniform spherical superstructures constructed from 1D MOF nanorods or carbon nanorods for applications in catalysis and energy storage
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|a Journal Article
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|a carbon nanorods
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4 |
|a formic acid dehydrogenation
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4 |
|a metal-organic framework nanorods
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| 650 |
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4 |
|a spherical superstructures
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1 |
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|a Kitta, Mitsunori
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Hong, Jinhua
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Suenaga, Kazutomo
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Tsumori, Nobuko
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Liu, Zheng
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Xu, Qiang
|e verfasserin
|4 aut
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| 773 |
0 |
8 |
|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 31(2019), 24 vom: 26. Juni, Seite e1900440
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
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| 773 |
1 |
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|g volume:31
|g year:2019
|g number:24
|g day:26
|g month:06
|g pages:e1900440
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|u http://dx.doi.org/10.1002/adma.201900440
|3 Volltext
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